936685

Grubbs Catalyst^® M102 ChemBeads

• Synonym(s): Grubbs Catalyst^® M102, Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium, Bis(tricyclohexylphosphine)benzylidine ruthenium(IV) dichloride ChemBeads, Dichloro(benzylidene)bis(tricyclohexylphosphine)ruthenium(II) ChemBeads, Grubbs Catalyst^® 1st Generation ChemBeads, Grubbs Catalyst^® M1a (C823) ChemBeads
• Empirical Formula (Hill Notation): C₄₃H₇₂Cl₂P₂Ru
• CAS Number: 172222-30-9
• Molecular Weight: 822.96
• UNSPSC Code: 12352103

Properties

• form: solid ()
• Quality Level: 100
• composition: 4-6 wt% loading of catalyst
• reaction suitability: reagent type: catalyst; core: ruthenium; reaction type: Ring-Opening Polymerization
• mp: 153 °C (dec.)
• SMILES string: Cl[Ru]([P](C1CCCCC1)(C2CCCCC2)C3CCCCC3)([P](C4CCCCC4)(C5CCCCC5)C6CCCCC6)(Cl)=CC7=CC=CC=C7; C[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru]
• InChI: 1S/2C18H33P.C7H6.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h2*16-18H,1-15H2;1-6H;2*1H;
• InChI key: AULHKSXXVKDNBT-UHFFFAOYSA-N

Description

General description

ChemBeads glass beads coated with Grubbs Catalyst^® M102.

Application

First metathesis catalyst to be widely used in organic synthesis. Useful for acyclic diene metathesis polymerization (ADMET), Ring-Opening Metathesis Polymerization (ROMP) of strained cyclic olefins, ring opening metathesis (ROM), olefin cross metathesis (CM) and ring closing metathesis (RCM) of terminal olefins under a variety of reactions conditions.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
For larger scale uses, product also available in powdered form (579726)

Features and Benefits

Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich
High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Legal Information

Grubbs Catalyst 7578

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Safety Information

• pictograms: GHS02
• signalword: Warning
• hcodes: H228
• pcodes: P210 - P240 - P241 - P280 - P370 + P378
• Hazard Classifications: Flam. Sol. 2
• Storage Class: 4.1B - Flammable solid hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable