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Sigma-Aldrich

Eriochrome® Black T

ACS reagent (indicator grade)

Synonym(s):

Mordant Black 11

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About This Item

Empirical Formula (Hill Notation):
C20H12N3NaO7S
CAS Number:
Molecular Weight:
461.38
Colour Index Number:
14645
Beilstein/REAXYS Number:
4121162
EC Number:
MDL number:
UNSPSC Code:
12171500
PubChem Substance ID:
NACRES:
NA.47

grade

ACS reagent (indicator grade)

Quality Level

form

powder

clarity of soln

passes test

technique(s)

titration: suitable

λmax

503 nm

suitability

passes test for complexometric indicator

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

SMILES string

[Na+].Oc1cc(c2cc(ccc2c1\N=N\c3ccc4ccccc4c3O)[N+]([O-])=O)S([O-])(=O)=O

InChI

1S/C20H13N3O7S.Na/c24-17-10-18(31(28,29)30)15-9-12(23(26)27)6-7-14(15)19(17)22-21-16-8-5-11-3-1-2-4-13(11)20(16)25;/h1-10,24-25H,(H,28,29,30);/q;+1/p-1/b22-21+;

InChI key

AMMWFYKTZVIRFN-QUABFQRHSA-M

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General description

Eriochrome® Black T is a hydroxyl-arylazo dye and is generally supplied as a monosodium salt. This dye exists as a dark violet powder with green metallic sheen. Eriochrome Black T is soluble in water and alcohol, but insoluble in common organic solvents. It is mainly used as an indicator in ethylenediaminetetraacetic acid (EDTA) method to determine hardness of water.
Eriochrome® Black T is used as an indicator for complexometric titrations. It functions as an acid-base indicator. Eriochrome® Black T forms complex with Ca2+ and Mg2+, but it binds more strongly to Mg2+ ions.

Application

Eriochrome® Black T has been used to determine the concentration of Ca2+ using complexometric titration method.

Legal Information

Eriochrome is a registered trademark of Huntsman Petrochemical, LLC

pictograms

Exclamation markEnvironment

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Warning

Hazard Classifications

Aquatic Chronic 2 - Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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