8.22287

Hydrogen peroxide 30%

(stabilized) for synthesis

• Synonym(s): Hydrogen peroxide solution, Perhydrol
• Empirical Formula (Hill Notation): H₂O₂
• CAS Number: 7722-84-1
• Molecular Weight: 34.01
• Beilstein/REAXYS Number: 3587191
• MDL number: MFCD00011333
• UNSPSC Code: 12352304

Properties

• vapor pressure: 18 hPa ( 20 °C); 23.3 mmHg ( 30 °C)
• Quality Level: 200
• form: liquid
• reaction suitability: reagent type: oxidant
• pH: 2-4 (20 °C in H₂O)
• bp: 107 °C/1013 hPa
• mp: -26 °C
• density: 1.11 g/cm³ at 20 °C
• storage temp.: 2-25°C
• SMILES string: OO
• InChI: 1S/H2O2/c1-2/h1-2H
• InChI key: MHAJPDPJQMAIIY-UHFFFAOYSA-N

Description

Application

Hydrogen peroxide 30% can be used as an oxidizing agent:

• To synthesize 5-bromo-2-nitropyridine from 5-bromo-2-aminopyridine in the presence of H₂SO₄.
• For the oxidation of aromatic and aliphatic sulfides to sulfoxides or sulfones.
• For the epoxidation of terminal olefins using a mixture of Na₂WO₄ dihydrate, (aminomethyl)phosphonic acid, and methyltrin-octylammonium hydrogensulfate.
• To prepare adipic acid via oxidation of cyclohexanone and cyclohexanol in the presence of H₂WO₄ as a catalyst.
• To convert cyclopentanone to δ-valerolactone via Baeyer−Villiger-oxidation in the presence of a solid acid catalyst.

Analysis Note

Assay (manganometric): 29.0 - 31.0 %
Density (d 20/4): 1.11 - 1.12 g/cm³

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H318
• pcodes: P280 - P305 + P351 + P338
• Hazard Classifications: Eye Dam. 1
• Storage Class: 5.1B - Oxidizing hazardous materials
• wgk_germany: WGK 1
• flash_point_f: not combustible
• flash_point_c: not combustible