C54007
Chloromethyl methyl sulfide
95%
Synonym(s):
Chlorodimethyl sulfide
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About This Item
Linear Formula:
CH3SCH2Cl
CAS Number:
Molecular Weight:
96.58
Beilstein/REAXYS Number:
1730851
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
assay
95%
form
liquid
refractive index
n20/D 1.498 (lit.)
bp
105 °C (lit.)
density
1.153 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CSCCl
InChI
1S/C2H5ClS/c1-4-2-3/h2H2,1H3
InChI key
JWMLCCRPDOIBAV-UHFFFAOYSA-N
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Application
Methylthiomethylating reagent for carbonyl and aromatic compounds. Methylene transfer reagent for iron(II) mediated cyclopropanation.
Caution
May darken in storage.
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
62.6 °F - closed cup
flash_point_c
17 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Synthesis, 276-276 (1994)
Chemistry Letters (Jpn), 653-653 (1993)
Manuel Algarra et al.
The journal of physical chemistry. A, 124(10), 1911-1921 (2020-02-14)
UV photodecomposition of azidomethyl methyl sulfide (AMMS) yields a transient S-methylthiaziridine which rapidly evolves to S-methyl-N-sulfenylmethanimine at 10 K. This species was detected by infrared matrix isolation spectroscopy. The mechanism of the photoreaction of AMMS has been investigated by a
Organic Syntheses, 70, 177-177 (1992)
[Mutagenic activity of chlorodimethylsulfide and some of its aniline derivatives].
M Vito et al.
Bollettino della Societa italiana di biologia sperimentale, 61(6), 917-923 (1985-06-30)
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