683175
Chiralyst P374
Umicore
Synonym(s):
Bis(norbornadiene)rhodium(I) tetrafluoroborate, Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate, Bis(norbornadiene)(tetrafluoroborato)rhodium, Rh(nbd)2BF4, Rh(nbd)2BF4
About This Item
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form
solid
reaction suitability
core: rhodium
reagent type: catalyst
mp
136.9-139.9 °C
SMILES string
[Rh+].F[B-](F)(F)F.C1C2C=CC1C=C2.C3C4C=CC3C=C4
InChI
1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1;+1/t2*6-,7+;;
InChI key
HAYDJWBQWOEERB-JAGGYEKFSA-N
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Application
- Lactones via the 1,4-addition of arylboronic acids to butenolide.
- Chiral β-aryl-substituted ketones and esters.
- β-aryloxycarboxylic esters from β-aryloxy-α,γ-unsaturated esters.
Legal Information
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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