671916

trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II)

98%

• Synonym(s): trans-Di(μ-acetato)bis[o-(di-o-tolyl-phosphino)benzyl]dipalladium(II), trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium, Herrmann′s catalyst, Herrmann′s palladacycle, Herrmann-Beller catalyst, Herrmann-Beller palladacycle, cataCXium^® C
• Empirical Formula (Hill Notation): C₄₆H₄₆O₄P₂Pd₂
• CAS Number: 172418-32-5
• Molecular Weight: 937.64
• MDL number: MFCD01075746
• UNSPSC Code: 12161600
• PubChem Substance ID: 329760447
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 98%
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; core: palladium; reagent type: ligand; reaction type: Asymmetric synthesis
• functional group: phosphine
• SMILES string: CC(=O)O[Pd]Cc1ccccc1P(c2ccccc2C)c3ccccc3C.CC(=O)O[Pd]Cc4ccccc4P(c5ccccc5C)c6ccccc6C
• InChI: 1S/2C21H20P.2C2H4O2.2Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;2*1-2(3)4;;/h2*4-15H,1H2,2-3H3;2*1H3,(H,3,4);;/q;;;;2*+1/p-2
• InChI key: YRGPDGDJUOTURS-UHFFFAOYSA-L

Description

General description

trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) is a useful catalyst for Heck reaction.

sold in collaboration with Solvias AG

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) is a useful catalyst for C-C and C-N cross coupling reaction.

Legal Information

US5831107

cataCXium is a registered trademark of Umicore AG & Co. KG

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)