511218

m-Toluidine

99%

• Synonym(s): 3-Methylaniline
• Linear Formula: CH₃C₆H₄NH₂
• CAS Number: 108-44-1
• Molecular Weight: 107.15
• Beilstein/REAXYS Number: 635944
• EC Number: 203-583-1
• MDL number: MFCD00007808
• UNSPSC Code: 12352100
• PubChem Substance ID: 24873429
• NACRES: NA.22

Properties

• assay: 99%
• refractive index: n20/D 1.567 (lit.)
• bp: 203-204 °C (lit.)
• density: 0.999 g/mL at 25 °C (lit.)
• SMILES string: Cc1cccc(N)c1
• InChI: 1S/C7H9N/c1-6-3-2-4-7(8)5-6/h2-5H,8H2,1H3
• InChI key: JJYPMNFTHPTTDI-UHFFFAOYSA-N

Description

General description

m-Toluidine (MT) is an aniline derivative that behaves as a fragile glass forming liquid. Its dielectric relaxation process, glass transition relaxation, relaxation modes and slow secondary relaxation have been studied. The analysis of MT crystalline phase by powder X-ray diffraction shows that it belongs to monoclinic space group, P2₁/c. Its structure is held together by N-H...N hydrogen bonds and van der Waals interactions.

Application

m-Toluidine may be used to form pyrrole/m-toluidine copolymers via oxidative polymerization.

Safety Information

• pictograms: GHS06,GHS08,GHS09
• signalword: Danger
• hcodes: H301 + H311 + H331,H373,H410
• pcodes: P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P314
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
• Storage Class: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• wgk_germany: WGK 3
• flash_point_f: 186.8 °F - closed cup
• flash_point_c: 86 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter