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495956

Sigma-Aldrich

trans-3-(tert-Butyldimethylsilyloxy)-N,N-dimethyl-1,3-butadien-1-amine

90%

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About This Item

Linear Formula:
(CH3)3CSi(CH3)2OC(=CH2)CH=CHN(CH3)2
CAS Number:
Molecular Weight:
227.42
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

90%

refractive index

n20/D 1.493 (lit.)

bp

234 °C (lit.)

density

0.878 g/mL at 25 °C (lit.)

functional group

amine

storage temp.

2-8°C

SMILES string

[H]\C(=C(\[H])C(=C)O[Si](C)(C)C(C)(C)C)N(C)C

InChI

1S/C12H25NOSi/c1-11(9-10-13(5)6)14-15(7,8)12(2,3)4/h9-10H,1H2,2-8H3/b10-9+

InChI key

NSCKABIMFIKUEF-MDZDMXLPSA-N

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

199.4 °F - closed cup

flash_point_c

93 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Preparation and Diels-Alder Reactivity of 1-Amino-3-siloxy-1,3-butadienes.
Kozmin SA and Rawal VH.
The Journal of Organic Chemistry, 62(16), 5252-5253 (1997)

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