303828

Ethylmagnesium chloride solution

2.0 M in THF

• Synonym(s): Chloroethylmagnesium
• Linear Formula: CH₃CH₂MgCl
• CAS Number: 2386-64-3
• Molecular Weight: 88.82
• Beilstein/REAXYS Number: 3647886
• MDL number: MFCD00000472
• UNSPSC Code: 12352103
• PubChem Substance ID: 24858148
• NACRES: NA.22

Properties

• form: liquid
• Quality Level: 100
• reaction suitability: reaction type: Grignard Reaction
• concentration: 2.0 M in THF
• density: 0.978 g/mL at 25 °C
• SMILES string: CC[Mg]Cl
• InChI: 1S/C2H5.ClH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
• InChI key: ZWNJJACKPNTXHY-UHFFFAOYSA-M

Description

Application

Ethylmagnesium chloride solution can be used:

• In Cp₂ZrCl₂ catalyzed ethylcarboxylation of alkenes using carbon dioxide to corresponding carboxylic acids.
• In the preparation of cyclobutylmagnesium carbenoids by reacting with 1-chlorocyclobutyl p-tolyl sulfoxides.

Safety Information

• pictograms: GHS02,GHS08,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H260,H314,H335,H336,H351
• pcodes: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• target_organs: Central nervous system, Respiratory system
• supp_hazards: EUH014,EUH019
• Storage Class: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• wgk_germany: WGK 1
• flash_point_f: 1.4 °F - closed cup
• flash_point_c: -17 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter