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(R)-(−)-1-Phenyl-1,2-ethanediol

Name: (<I>R</I>)-(−)-1-Phenyl-1,2-ethanediol
Brand: ALDRICH

99%

Synonym(s):

(−)-Styrene glycol, (R)-(−)-Phenylethylene glycol

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About This Item

Linear Formula:

HOCH₂CH(C₆H₅)OH

CAS Number:

16355-00-3

Molecular Weight:

138.16

Beilstein/REAXYS Number:

2355547

MDL number:

MFCD00064262

UNSPSC Code:

12352002

PubChem Substance ID:

24858238

NACRES:

NA.22

assay

99%

optical activity

[α]20/D −69°, c = 1 in chloroform

bp

272-274 °C (lit.)

mp

64-67 °C (lit.)

SMILES string

OC[C@H](O)c1ccccc1

InChI

1S/C8H10O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8-10H,6H2/t8-/m0/s1

InChI key

PWMWNFMRSKOCEY-QMMMGPOBSA-N

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Related Categories

Chiral Catalysts & Ligands

Sterile Filters

Application

Intermediate for the synthesis of chiral phosphine catalysts for asymmetric hydrogenations.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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J. Chem. Soc. Perkin Trans. II, 489-489 (1982)

The Journal of Organic Chemistry, 44, 1729-1729 (1979)

Simultaneous determination of phenylglyoxylic acid, mandelic acid, styrene glycol and hippuric acid in primary culture of rat hepatocytes incubate by high-performance liquid chromatography.

Jin-Zhao Wang et al.

Biomedical chromatography : BMC, 21(5), 497-501 (2007-03-16)

A simple HPLC method for the simultaneous determination of phenylglyoxylic acid (PGA), mandelic acid (MA), styrene glycol (SG) and hippuric acid (HA) in cell culture medium was developed. Analysis was performed on a C(18) column with a mobile phase composed

[Construction of an enzyme-coupled system consisting of (R)- and (S)-specific carbonyl reductases for one-step preparation of (S)-1-phenyl-1,2-ethanediol].

Rongzhen Zhang et al.

Wei sheng wu xue bao = Acta microbiologica Sinica, 49(2), 204-209 (2009-05-19)

To prepare (S)-1-phenyl-1,2-ethanediol by a one-step method, we constructed an enzyme coupled system consisting of (R)- and (S)-specific carbonyl reductases in Escherichia coli. The genes coding (R)- and (S)-specific carbonyl reductases from Candida parapsilosis were inserted into a co-expression vector

Enhancement of Candida parapsilosis catalyzing deracemization of (R,S)-1-phenyl-1,2-ethanediol to its (S)-enantiomer by a highly productive "two-in-one" resin-based in situ product removal strategy.

Qingsen Hu et al.

Bioresource technology, 101(21), 8461-8463 (2010-06-25)

In this study, a highly efficient process for Candida parapsilosis-catalyzed deracemization of racemic 1-phenyl-1,2-ethanediol (PED) was described, based on a resin-based in situ substrate feeding and product removal (ISSFPR) methodology. The resin H103 was selected and used to keep the

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