287784

(1R,2R,3S,5R)-(−)-Pinanediol

99%

• Synonym(s): (−)-2-Hydroxyisopinocampheol, [1R-(1α,2α,3α,5α)]-2,6,6-Trimethylbicyclo[3.1.1]heptane-2,3-diol
• Empirical Formula (Hill Notation): C₁₀H₁₈O₂
• CAS Number: 22422-34-0
• Molecular Weight: 170.25
• Beilstein/REAXYS Number: 2039144
• MDL number: MFCD09955216
• UNSPSC Code: 12352001
• PubChem Substance ID: 24857292
• NACRES: NA.22

Properties

• Quality Level: 200
• assay: 99%
• optical activity: [α]21/D −8.6°, c = 6.5 in toluene
• optical purity: ee: 97% (GLC)
• bp: 101-102 °C/1 mmHg (lit.)
• mp: 57-59 °C (lit.)
• SMILES string: CC1(C)[C@H]2C[C@H](O)[C@](C)(O)[C@@H]1C2
• InChI: 1S/C10H18O2/c1-9(2)6-4-7(9)10(3,12)8(11)5-6/h6-8,11-12H,4-5H2,1-3H3/t6-,7-,8+,10-/m1/s1
• InChI key: MOILFCKRQFQVFS-BDNRQGISSA-N

Description

Application

Used to prepare chiral double allylation reagents.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: 230.0 °F - closed cup
• flash_point_c: 110 °C - closed cup
• ppe: Eyeshields, Gloves, type N95 (US)