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237906

Sigma-Aldrich

Phenyl chloroformate

97%

Synonym(s):

Chloroformic acid phenyl ester

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About This Item

Linear Formula:
ClCOOC6H5
CAS Number:
1885-14-9
Molecular Weight:
156.57
Beilstein/REAXYS Number:
606778
EC Number:
217-547-8
MDL number:
MFCD00000637
UNSPSC Code:
12352100
PubChem Substance ID:
24854276
NACRES:
NA.22

vapor density

1 (vs air)

Quality Level

100

vapor pressure

1.22 psi ( 20 °C)
1.67 psi ( 55 °C)

assay

97%

form

liquid

refractive index

n20/D 1.511 (lit.)

bp

74-75 °C/13 mmHg (lit.)

density

1.248 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

ClC(=O)Oc1ccccc1

InChI

1S/C7H5ClO2/c8-7(9)10-6-4-2-1-3-5-6/h1-5H

InChI key

AHWALFGBDFAJAI-UHFFFAOYSA-N

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General description

Kinetics of spontaneous hydrolysis of phenyl chloroformate has been studied in water-ethylene glycol, cationic, zwitterionic, nonionic and anionic micellar solutions.

Application

Phenyl chloroformate has been used in the synthesis of poly(2-(phenoxycarbonyloxy)ethylmethacrylate) and phenyl-(4-vinylphenyl)carbonate.

pictograms

CorrosionSkull and crossbones
GHS05,GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

156.2 °F - closed cup

flash_point_c

69 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Amalia Rodríguez et al.
Langmuir : the ACS journal of surfaces and colloids, 20(23), 9945-9952 (2004-11-03)
The spontaneous hydrolysis of phenyl chloroformate was studied in water-ethylene glycol, EG, cationic, zwitterionic, nonionic, and anionic micellar solutions, the surfactants being tetradecyltrimethylammonium bromide, tetradecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate, tricosaoxyethylene glycol ether, and sodium dodecyl sulfate. The dependence of the observed rate constant on
Functional polymethacrylates as bacteriostatic polymers.
Adelmann R, et al.
Eur. Polymer J., 45(11), 3093-3107 (2009)
B Boettcher et al.
Analytical biochemistry, 138(2), 449-450 (1984-05-01)
An improved synthesis of L-2- oxothiazolidine -4-carboxylic acid is described. The new procedure, which leads to excellent yields of product, does not require the use of phosgene. The new method is thus less hazardous than the original one, and is
R K Keller et al.
Biochemistry, 20(20), 5831-5836 (1981-09-29)
A sensitive assay is described for quantitating dolichyl phosphate (Dol-P), the polyprenyl phospholipid which participates in N-linked glycosylation. The assay is based on a novel reaction of alkyl phosphates with phenyl chloroformate in which a monosubstituted mixed anhydride of phosphoric
Luis García-Río et al.
Langmuir : the ACS journal of surfaces and colloids, 21(17), 7672-7679 (2005-08-11)
A study was carried out on the solvolysis of substituted phenyl chloroformates in AOT/isooctane/water microemulsions. (AOT is the sodium salt of bis(2-ethyhexyl)sulfosuccinate.) The results obtained have been interpreted by taking into account the distribution of the chloroformates between the continuous
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