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Sigma-Aldrich

1-Bromo-2-chloroethane

98%

Synonym(s):

Ethylene bromochloride, Ethylene chlorobromide

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About This Item

Linear Formula:
ClCH2CH2Br
CAS Number:
107-04-0
Molecular Weight:
143.41
Beilstein/REAXYS Number:
605265
EC Number:
203-456-0
MDL number:
MFCD00000962
UNSPSC Code:
12352100
PubChem Substance ID:
24853925
NACRES:
NA.22

assay

98%

form

liquid

refractive index

n20/D 1.488 (lit.)

bp

106-107 °C (lit.)

mp

−18-−14 °C (lit.)

solubility

water: soluble

density

1.723 g/mL at 25 °C (lit.)

SMILES string

ClCCBr

InChI

1S/C2H4BrCl/c3-1-2-4/h1-2H2

InChI key

IBYHHJPAARCAIE-UHFFFAOYSA-N

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General description

Dissociative double ionization and multi-photon ionization of 1-bromo-2-chloroethane (BCE) irradiated by the 800nm femtosecond laser field has been investigated by dc-slice imaging technology. Conformational properties of BCE in several zeolites such as silicalite-1, siliceous Y, Na-Y and zeolite L have been investigated by FT-Raman spectroscopy.

Application

1-Bromo-2-chloroethane was used in regio- and diastereoselective synthesis of 2-alkylidenetetrahydrofurans.

pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Carc. 1B - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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P Langer et al.
The Journal of organic chemistry, 66(18), 6057-6063 (2001-09-01)
The domino C,O-cyclodialkylation reaction of dilithiated 1,3-dicarbonyl compounds with 1,4-dibromo-2-butene resulted in regio- and diastereoselective formation of 2-alkylidene-5-vinyltetrahydrofurans. The cyclization of 1,3-dicarbonyl dianions with 1-bromo-2-chloroethane regio- and diastereoselectively afforded 2-alkylidenetetrahydrofurans under thermodynamic reaction control.
Yan Yang et al.
The Journal of chemical physics, 135(6), 064303-064303 (2011-08-17)
The dissociative double ionization and multi-photon ionization of 1-bromo-2-chloroethane (BCE) irradiated by the 800 nm femtosecond laser field have been investigated by dc-slice imaging technology. The charged parent ion ratio [BCE(2+)]/[BCE(+)] was measured, and the corresponding ionization process including non-sequential
R D Storer et al.
Carcinogenesis, 4(11), 1491-1494 (1983-11-01)
Hepatic DNA damage was demonstrated by alkaline DNA unwinding/hydroxylapatite batch chromatography in male B6C3F1 mice treated with non-necrogenic doses of 1,2-dichloroethane, 1-bromo-2-chloroethane, and 1,2-dibromoethane. Intraperitoneal administration of 0.5 mmol/kg of 1-bromo-2-chloroethane and 1,2-dibromoethane produced similar levels of DNA damage. A
J Plenge et al.
Physical chemistry chemical physics : PCCP, 13(19), 8705-8714 (2011-03-29)
We report on the coherent control of the ultrafast ionization and fragmentation dynamics of the bromochloroalkanes C(2)H(4)BrCl and C(3)H(6)BrCl using shaped femtosecond laser pulses. In closed-loop control experiments on bromochloropropane (C(3)H(6)BrCl) the fragment ion yields of CH(2)Cl(+), CH(2)Br(+), and C(3)H(3)(+)
Haiyan Wang et al.
Langmuir : the ACS journal of surfaces and colloids, 25(14), 8042-8050 (2009-04-21)
The conformational properties of 1-bromo-2-chloroethane (BCE) in several representative zeolites including silicalite-1, siliceous Y (Si-Y), Na-Y, and zeolite L have been investigated by FT-Raman spectroscopy in combination with thermogravimetric analysis. The results indicate that the conformational and dynamic behavior of
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