226173

(1S)-(−)-Camphanic chloride

98%

• Synonym(s): (−)-Camphanoyl chloride, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride
• Linear Formula: C₁₀H₁₃O₃Cl
• CAS Number: 39637-74-6
• Molecular Weight: 216.66
• Beilstein/REAXYS Number: 3590860
• EC Number: 254-552-4
• MDL number: MFCD00135626
• UNSPSC Code: 12352005
• PubChem Substance ID: 24853548
• NACRES: NA.22

Properties

• Quality Level: 200
• assay: 98%
• optical activity: [α]23/D −18±1°, c = 2 in dioxane
• mp: 71-73 °C (lit.)
• functional group: acyl chloride; ester
• storage temp.: 2-8°C
• SMILES string: CC1(C)[C@@]2(C)CC[C@@]1(OC2=O)C(Cl)=O
• InChI: 1S/C10H13ClO3/c1-8(2)9(3)4-5-10(8,6(11)12)14-7(9)13/h4-5H2,1-3H3/t9-,10+/m0/s1
• InChI key: PAXWODJTHKJQDZ-VHSXEESVSA-N

Description

General description

(1S)-(-)-Camphanic chloride is a chiral derivatizing agent. It can be prepared by reacting (-)-(1S,4R)-camphanic acid with thionyl chloride.

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges