125423

1,4-Cyclohexanedione

98%

• Synonym(s): 1,4-Dioxocyclohexane, Cyclohexan-1,4-dione, Tetrahydroquinone
• Linear Formula: C₆H₈(=O)₂
• CAS Number: 637-88-7
• Molecular Weight: 112.13
• Beilstein/REAXYS Number: 774152
• EC Number: 211-306-0
• MDL number: MFCD00001606
• UNSPSC Code: 12352100
• PubChem Substance ID: 24847666
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 98%
• form: solid
• mp: 77-78.5 °C (lit.)
• functional group: ketone
• SMILES string: O=C1CCC(=O)CC1
• InChI: 1S/C6H8O2/c7-5-1-2-6(8)4-3-5/h1-4H2
• InChI key: DCZFGQYXRKMVFG-UHFFFAOYSA-N

Description

General description

1,4-Cyclohexanedione(CHD) undergoes uncatalyzed oscillatory reactions during oxidation by acidic bromate in nitric acid and sulphuric acid solution. It reacts with acidic bromate to form 1,4-dihydroxybenzene which on further oxidation and bromination yields 1,4-benzoquinone and bromoorganics.

Application

1,4-Cyclohexanedione has been used to study the influence of visible light on the bromate-1,4-cyclohexanedione-ferroin oscillating reaction.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: 269.6 °F - closed cup
• flash_point_c: 132 °C - closed cup
• ppe: Eyeshields, Gloves, type N95 (US)