115541

(R)-(+)-α-Methylbenzylamine

98%

• Synonym(s): (R)-(+)-1-Phenylethylamine
• Linear Formula: C₆H₅CH(CH₃)NH₂
• CAS Number: 3886-69-9
• Molecular Weight: 121.18
• Beilstein/REAXYS Number: 2410916
• EC Number: 223-423-4
• MDL number: MFCD00064405
• UNSPSC Code: 12352116
• PubChem Substance ID: 24847222
• NACRES: NA.22

Properties

• vapor pressure: 0.5 mmHg ( 20 °C)
• Quality Level: 200
• assay: 98%
• optical activity: [α]23/D +38°, neat
• optical purity: ee: 96% (GLC)
• refractive index: n20/D 1.526 (lit.)
• bp: 187-189 °C (lit.)
• density: 0.952 g/mL at 20 °C (lit.)
• functional group: amine; phenyl
• storage temp.: 2-8°C
• SMILES string: C[C@@H](N)c1ccccc1
• InChI: 1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m1/s1
• InChI key: RQEUFEKYXDPUSK-SSDOTTSWSA-N

Description

Application

(R)-(+)-α-Methylbenzylamine is a chiral amine that may be used as a substrate to synthesize (S)-α-amino phosphonates, R-α-aminonitriles, N-{(S)-[cyclohexan-(S)-2-ol]}-(R)-α-methylbenzyl amine and N-{(R)-[cyclohexan-(R)-2-ol]}-(R)-α-methylbenzyl amine. In the presence of boric acid, it can be used in the resolution of racemic 1,1′-bi-2-naphthol.

Safety Information

• pictograms: GHS05,GHS07
• signalword: Danger
• hcodes: H302 + H312,H314
• pcodes: P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P362 + P364
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 1
• flash_point_f: 158.0 °F - closed cup
• flash_point_c: 70 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter