100900

4-Bromoaniline

97%

• Synonym(s): 1-Amino-4-bromobenzene, p-Bromoaniline
• Linear Formula: BrC₆H₄NH₂
• CAS Number: 106-40-1
• Molecular Weight: 172.02
• Beilstein/REAXYS Number: 742031
• EC Number: 203-393-9
• MDL number: MFCD00007822
• UNSPSC Code: 12352100
• PubChem Substance ID: 24846426
• NACRES: NA.22

Properties

• Quality Level: 200
• assay: 97%
• form: solid
• mp: 56-62 °C (lit.)
• functional group: bromo
• SMILES string: Nc1ccc(Br)cc1
• InChI: 1S/C6H6BrN/c7-5-1-3-6(8)4-2-5/h1-4H,8H2
• InChI key: WDFQBORIUYODSI-UHFFFAOYSA-N

Description

Application

4-Bromoaniline can be used as a starting material for the preparation of:

• Sharpless asymmetric ligands for dihydroxylation of alkenes.
• Chemical intermediates such as 4-bromophenyl azide , 4-bromonitrosobenzene , N-(4-bromophenyl)-4-methylbenzenesulfonamide , and ethyl 4-(4-(4-methylphenylsulfonamido)phenyl)butanoate.

It is also used in the surface functionalization of carbon nanotubes via preparation of 4-bromo benzenediazonium derivatives.

Safety Information

• pictograms: GHS06,GHS08,GHS09
• signalword: Danger
• hcodes: H302,H311 + H331,H373,H410
• pcodes: P273 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P311 - P314
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Faceshields, Gloves