Detection of emerging contaminants (UV filters, UV stabilizers and musks) in marine mussels from Portuguese coast by QuEChERS extraction and GC-MS/MS.

Detection of emerging contaminants (UV filters, UV stabilizers and musks) in marine mussels from Portuguese coast by QuEChERS extraction and GC-MS/MS.

The Science of the total environment (2014-06-20)

M Picot Groz, M J Martinez Bueno, D Rosain, H Fenet, C Casellas, C Pereira, V Maria, M J Bebianno, E Gomez

ABSTRAKT

The UV filters and musk fragrances have come into focus because these compounds are contained and increasingly used not only in sunscreen products but also in many products of daily use, such as cosmetics, skin creams, plastics or varnish. In view of this, the main objective of the present work was to develop and validate a method for the determination of three UV filters, two UV stabilizers and four musks in mussel samples (Mytilus galloprovincialis). The procedure combined a QuEChERS (Quick, Easy, Cheap, Effective, Rugged, and Safe) extraction method with an analysis by gas chromatography-tandem mass spectrometry (GC-MS/MS). The methodology allowed the determination of target analytes at trace concentration levels (ng/g), with mean recoveries ranging from 91 to 112%. A monitoring study was conducted in four beaches in the Portuguese coast which are impacted by recreational activities and outflow of treated waste water effluents in rivers. The results are used to assess the occurrence of UV filters in comparison with UV stabilizers and musk fragrances which indicate other activities than bathing.

MATERIAŁY

Numer produktu

Marka

Opis produktu

55227-U

Supelco

Supel^™ QuE, Citrate Extraction Tube, pk of 50, suitable for EN 15662

55228-U

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55229-U

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Supel^™ QuE, PSA/C18 Tube, pk of 50, suitable for EN 15662:2008 per BS

55234-U

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Supel^™ QuE, Acetate Tube, pk of 50, AOAC^® 2007.01

55288-U

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Supel^™ QuE, PSA/C18 Tube, pack of 100, AOAC^® 2007.01

55289-U

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Supel^™ QuE, PSA/C18/ENVI-Carb Tube, pack of 100, AOAC^® 2007.01

55287-U

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Supel^™ QuE, PSA Tube, pack of 100, AOAC^® 2007.01

55284-U

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Supel^™ QuE, Z-Sep/C18 Tube, centrifuge tube volume 2 mL, pack of 100

55470-U

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55439-U

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55474-U

Supelco

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55446-U

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Supel^™ QuE, PSA/ENVI-Carb Tube 1, pk of 50, suitable for EN 15662:2008 per BS, centrifuge tube volume 15 mL , Shaker Compatible

55464-U

Supelco

Supel^™ QuE, PSA/ENVI-Carb Tube 2, pk of 50, suitable for EN 15662:2008 per BS, centrifuge tube volume 15 mL , Shaker Compatible

55466-U

Supelco

Supel^™ QuE, PSA Tube, pk of 50, AOAC^® 2007.01, centrifuge tube volume 15 mL , Shaker Compatible

55408-U

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Supel^™ QuE, Z-Sep+ Tube, centrifuge tube volume 2 mL, pack of 100 ea

55411-U

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55506-U

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55511-U

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Supel^™ QuE, Z-Sep+ with MgSO₄Tube, pk of 50, centrifuge tube volume 15 mL , Shaker Compatible

55491-U

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Supel^™ QuE, Z-Sep Tube, pk of 50, centrifuge tube volume 15 mL , Shaker Compatible

55486-U

Supelco

Supel^™ QuE, Z-Sep+ Tube, pk of 50, centrifuge tube volume 15 mL , Shaker Compatible