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Butterfly-Shaped Thiophene-Pyridine Hybrids: Green Electroluminescence and Large Third-Order Optical Nonlinearities.

ChemPlusChem (2020-08-15)
Viprabha Kakekochi, Sathish Chatnahalli Gangadharappa, P P Nikhil, Keloth Chandrasekharan, Vibhu Darshan, K N Narayanan Unni, Udaya Kumar Dalimba
ABSTRAKT

A set of four symmetric, butterfly-shaped 4-(4-(decyloxy)phenyl)-2,6-di(thiophen-2-yl)pyridine (TPY) derivatives 2TPA-TPY (TPY center and triphenylamine end groups), 2CBZ-TPY (TPY center and N-ethyl carbazole end groups), 2TPY-TPA (triphenylamine center and TPY at the periphery) and 2TPY-CBZ (N-ethyl carbazole center and TPY at the periphery) was synthesized. The molecules show reverse saturable absorption (RSA) which is consistent with two-photon absorption (2PA) associated with excited-state absorption (ESA) when excited using a 532 nm laser beam. The molecules 2TPA-TPY and 2TPY-TPA possess extremely low limiting thresholds of 1.73 and 2.68 J cm-2 , respectively. An organic light-emitting diode (OLED) fabricated from 2TPA-TPY exhibits green emission with a maximum luminance of 207 cd m-2 , a current efficiency (ηCE ) of 1.51cd A-1 , a maximum power efficiency (ηPmax ) of 0.46 lm W-1 and an external quantum efficiency (ηEQE ) of 0.48 % at 100 cd m-2 .

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Sigma-Aldrich
4-(Diphenylamino)benzaldehyde, 97%
Sigma-Aldrich
4,4′-Diformyltriphenylamine, 95%