208574
Molecular sieves, 3 Å
beads, 4-8 mesh
Synonim(y):
Molecular Sieve UOP Type 3Å
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About This Item
Wzór liniowy:
KnNa12-n[(AlO2)12(SiO2)12] · xH2O
Numer CAS:
Numer MDL:
Kod UNSPSC:
23201100
eCl@ss:
32110204
NACRES:
NB.24
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Opis ogólny
Molecular sieves are crystalline metal aluminosilicates having a 3-dimensional interconnecting network of silica and alumina tetrahedra. Natural water of hydration is removed from this network by heating to produce uniform cavities which selectively adsorb molecules of a specific size. The 3A form is made by substituting potassium cations for the inherent sodium ions of the 4A structure, reducing the effective pore size to ~3Å, excluding diameter >3Å, e.g., ethane. The 4 to 8-mesh type is normally used in gas-phase applications. Molecular sieves are considered a universal drying agent in polar and nonpolar media.
Zastosowanie
Molecular sieves have been used for the drying of dimethyl sulfoxide.
They may also be used in the following:
They may also be used in the following:
- Synthesis of ecteinascidin 743 (a potential marine-derived antitumor agent).
- Preparation of vanillyl nonanoate (a model capsinoid compound).
- Highly enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes.
Molecular sieves, 3 Å may be used in the following processes:
- As a general-purpose drying agent in polar and nonpolar media.
- Commercial dehydration of unsaturated hydrocarbon streams, including cracked gas, propylene, butadiene, acetylene
- Drying polar liquids such as methanol and ethanol.
- Adsorption of molecules such as NH3 and H2O from a N2/H2 flow.
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Kod klasy składowania
13 - Non Combustible Solids
Klasa zagrożenia wodnego (WGK)
WGK 3
Temperatura zapłonu (°F)
Not applicable
Temperatura zapłonu (°C)
Not applicable
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Chiral phosphoric acid catalyzed enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes: cooperative effect of 3 A molecular sieves.
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Corey EJ, et al.
Journal of the American Chemical Society, 118(38), 9202-9203 (1996)
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Capsinoids are a novel group of compounds produced by the Capsicum plant. We synthesized a capsinoid by the lipase-catalyzed esterification of vanillyl alcohol with fatty acid derivatives in an organic solvent. The use of seven out of 17 commercially available
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