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Merck
모든 사진(2)

주요 문서

89456

Supelco

4,4′,4″,4″′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonic acid)

for spectrophotometric det. of transition metals, ≥95.0%

동의어(들):

meso-Tetraphenylporphine-4,4′,4″,4″′-tetrasulfonic acid

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About This Item

실험식(Hill 표기법):
C44H30N4O12S4
CAS Number:
Molecular Weight:
934.99
Beilstein:
4227566
MDL number:
UNSPSC 코드:
12000000
PubChem Substance ID:
NACRES:
NA.21

Quality Level

분석

≥95.0% (HPLC)
≥95.0%

양식

powder

품질

for spectrophotometric det. of transition metals

기술

UV/Vis spectroscopy: suitable

불순물

~9% water

SMILES string

OS(=O)(=O)c1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(cc4)S(O)(=O)=O)c5ccc([nH]5)c(-c6ccc(cc6)S(O)(=O)=O)c7ccc(n7)c(-c8ccc(cc8)S(O)(=O)=O)c9ccc2[nH]9

InChI

1S/C44H30N4O12S4/c49-61(50,51)29-9-1-25(2-10-29)41-33-17-19-35(45-33)42(26-3-11-30(12-4-26)62(52,53)54)37-21-23-39(47-37)44(28-7-15-32(16-8-28)64(58,59)60)40-24-22-38(48-40)43(36-20-18-34(41)46-36)27-5-13-31(14-6-27)63(55,56)57/h1-24,45,48H,(H,49,50,51)(H,52,53,54)(H,55,56,57)(H,58,59,60)/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

InChI key

PBHVCRIXMXQXPD-LWQDQPMZSA-N

애플리케이션

4,4′,4′′,4′′′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonic acid) [tetrasodium salt hydrate, TPPS] has been used in preparing Co–Al LDH/Fe(III)-TPPS film modified electrode; for demonstrating reversible redox peak attribution to Co(III)/Co(II), with iron(III) porphyrin; making it mediator for electron transfer.

포장

Bottomless glass bottle. Contents are inside inserted fused cone.

분석 메모

max. Absorption (in Methanol): 412-416 nm

기타 정보

Reagent for the spectrophotometric determination of ultra trace amounts of transition metals; determination by capillary zone electrophoresis

픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


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문서 라이브러리 방문

Ali Farajtabar et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 83(1), 213-220 (2011-09-17)
The solvatochromic properties of the free base and the protonated 5, 10, 15, 20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS) were studied in pure water, methanol, ethanol (protic solvents), dimethylsulfoxide, DMSO, (non-protic solvent), and their corresponding aqueous-organic binary mixed solvents. The correlation of the empirical
Jun Ding et al.
Journal of biomedical nanotechnology, 6(6), 683-686 (2011-03-03)
In this paper, we present the preparation and characterization of organic dye-coated magnetic particles and its application as magnetic resonance imaging (MRI) and photodynamic therapy (PDT) agent. We have coated the surface of Fe3O4 magnetic nanoparticles by meso-tetra(4-sulfonatophenyl) porphyrin dihydrochloride
Kunio Kawamura et al.
Talanta, 84(5), 1318-1322 (2011-06-07)
A new type of flow injection analysis (FIA) system combined with an extremely high temperature reactor, namely hydrothermal flow injection analysis (HT-FIA), has been successfully constructed for the first time. Fundamental characteristics of HT-FIA system, such as limit temperature, pressure
S Almeda et al.
Journal of chromatography. A, 1216(34), 6256-6258 (2009-07-22)
Although capillary electrophoresis (CE) with photometric detection is a well-established technique for the determination of various inorganic ions, its limited sensitivity has hindered greater development in this area. In this work, we used a mixture of metals consisting of Co(II)
Guilherme M Gelfuso et al.
European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 77(2), 249-256 (2010-12-02)
Meso-tetra-(N-methylpiridinium-4-yl)-porphyrin (TMPyP) and meso-tetra-(4-sulfonatophenyl)-porphyrin (TPPS(4)) are photosensitizing drugs (PS) used in photodynamic therapy (PDT). Based on the fact that these compounds present similar chemical structures but opposite charges at pH levels near physiological conditions, this work aims to evaluate the

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