추천 제품
Grade
for chiral derivatization
Quality Level
분석
≥99.0% (AT)
≥99.0%
광학 활성
[α]20/D +132±2°, c = 6% in chloroform
광학 순도
enantiomeric ratio: ≥99.5:0.5 (GC)
품질
LiChropur™
기술
HPLC: suitable
refractive index
n20/D 1.469 (lit.)
n20/D 1.469
bp
213-214 °C (lit.)
density
1.35 g/mL at 25 °C (lit.)
배송 상태
wet ice
저장 온도
−20°C
SMILES string
CO[C@@](C(Cl)=O)(c1ccccc1)C(F)(F)F
InChI
1S/C10H8ClF3O2/c1-16-9(8(11)15,10(12,13)14)7-5-3-2-4-6-7/h2-6H,1H3/t9-/m1/s1
InChI key
PAORVUMOXXAMPL-SECBINFHSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
애플리케이션
Determination of absolute configuration of stereogenic carbinol carbons; doi:10.1038/nprot.2007.354
포장
Bottomless glass bottle. Contents are inside inserted fused cone.
법적 정보
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point (°F)
192.2 °F - closed cup
Flash Point (°C)
89 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Choose from one of the most recent versions:
Journal of chromatography, 307(2), 335-342 (1984-05-11)
High-performance liquid chromatography (HPLC) was employed for resolution of enantiomers of chiral ring-substituted 1-phenyl-2- aminopropanes (amphetamines) and 1-phenylethylamine following derivatization with four chiral reagents: (R)-(+)-1-phenylethyl isocyanate ( PEIC ), (-)-alpha-methoxy-alpha-(trifluoromethyl)phenylacetyl chloride ( MTPA X Cl), 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl isothiocyanate ( GITC )
Nature protocols, 2(10), 2451-2458 (2007-10-20)
This protocol details the most commonly used nuclear magnetic resonance (NMR)-based method for deducing the configuration of otherwise unknown stereogenic, secondary carbinol (alcohol) centers (R1R2CHOH (or the analogous amines where OH is replaced by NH2)). This 'Mosher ester analysis' relies
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