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Merck
모든 사진(1)

주요 문서

923222

Sigma-Aldrich

Poly(9,9-dioctylfluorenyl-2,7-diyl) end capped with dimethylphenyl

greener alternative

Mw 50,000-150,000 by GPC

동의어(들):

PFO-DMP

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About This Item

Linear Formula:
C16H18(C29H40)n
CAS Number:
MDL number:
UNSPSC 코드:
12352103
NACRES:
NA.23

설명

PL: 421 nm in THF

Quality Level

분자량

Mw 50,000-150,000 by GPC

환경친화적 대안 제품 특성

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

밴드 간극

2.5 eV

solubility

THF: soluble
chlorobenzene: soluble
chloroform: soluble
dichlorobenzene: soluble

λmax

368 nm in THF

오비탈 에너지

HOMO -5.3 eV 
LUMO -2.8 eV 

환경친화적 대안 카테고리

일반 설명

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Hole transport organic materials allow perfect energy level alignment with the absorber layer and therefore efficient charge collection, are prone to degradation in ambient conditions.Click here for more information.

애플리케이션

Highly emissive poly(9,9-dioctylfluorenyl-2, 7-diyl) end capped with dimethylphenyl (PFO-DMP) is a conjugated polymer with white light emision, remarkable thermal stability and high photo- and electroluminescence efficiency. PFO-DMP was successfully demonstrated in textile digital printing for organic light emission devices (OLEDs) , as well as in high voltage composite separator in Lithium batteries at high rates and low temperatures.
PFO-DMPP can be used as an active material in the fabrication of LEDs. The modification with dimethylphenyl end-capping groups can enhance the charge injection and transport characteristics, leading to improved device efficiency and stability. It can be used in applications in OPV devices, particularly as a donor material. The end-capping with dimethylphenyl groups can modify the energy levels and molecular packing, impacting the optical and electrical properties. PFO-DMPP can be utilized as an active layer in organic thin-film transistors (OTFTs) due to its improved charge transport characteristics. The end-capping groups help to enhance the carrier mobility and improve the performance of the transistors. This modification can influence the power conversion efficiency of the OPV cells.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

Overcharge Protection for 4 V Lithium Batteries at High Rates and Low Temperatures.
Chen G, et al.
Journal of the Electrochemical Society, 157, A735-A740 (2010)
Efficient white light emission in conjugated polymer homojunctions.
Ho G K, et al.
Applied Physics Letters, 85, 4576-4578 (2004)
Characterization of digital textile printing and polymer blend (PFO-DMP:P3HT) for application in manufacture of organic diodes emitting white light - WOLEDS.
Da Silva M A T, et al.
Optical Materials, 62, 119-131 (2016)

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