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915319

Aminosupersilane

Name: Aminosupersilane
Brand: ALDRICH

동의어(들):

N-(Adamantan-1-yl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilan-2-amine

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About This Item

실험식(Hill 표기법):

C₁₉H₄₃NSi₄

Molecular Weight:

397.89

UNSPSC 코드:

12352116

NACRES:

NA.06

추천 제품

Slide 1 of 10

1 of 10

Sigma-Aldrich

283657

Nickel(II) acetylacetonate

Sigma-Aldrich

360716

Tris(trimethylsilyl)silane

Sigma-Aldrich

747793

(Ir[dF(CF₃)ppy]₂(dtbpy))PF₆

Sigma-Aldrich

902489

Tris(trimethylsilyl)silanol

Sigma-Aldrich

403393

Nickel(II) bis(2,2,6,6-tetramethyl-3,5-heptanedionate)

Sigma-Aldrich

197602

Quinuclidine

Sigma-Aldrich

765910

Potassium tri(3,5-dimethyl-1-pyrazolyl)borohydride

Sigma-Aldrich

915297

4CzIPN

Sigma-Aldrich

257532

2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine iron(III) chloride

Sigma-Aldrich

20615

2-tert-Butyl-1,1,3,3-tetramethylguanidine

양식

powder

Quality Level

100

애플리케이션

Aminosupersilane has been demonstrated by the MacMillan lab to be a necessary reagent in the dual catalytic nickel/photoredox cross-electrophile coupling of unactivated alkyl chlorides. The increased nucleophilicity of aminosupersilane, as compared to other organosilane reagents, is key to activating the alkyl chloride for chlorine atom abstraction.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)