911402

(CyPAd-DalPhos)NiCl(otol)

≥95%

• 동의어(들): 8-(2-(Dicyclohexylphosphaneyl)phenyl)-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphaadamantane nickel(II) o-tolyl chloride
• 실험식(Hill 표기법): C₃₅H₄₉ClNiO₃P₂
• CAS Number: 2115838-60-1
• Molecular Weight: 673.86
• UNSPSC 코드: 12352200
• NACRES: NA.22

속성

• 분석: ≥95%
• 형태: powder
• 반응 적합성: reagent type: catalyst; reaction type: Cross Couplings
• mp: 193-197 °C

설명

애플리케이션

(CyPAd-DalPhos)NiCl(otol) is an air stable precatalyst developed in the Stradiotto lab used for C(sp²)-O coupling and N-arylation reactions.

기타 정보

Technology Spotlight: DalPhos ligands

Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C–O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols

Nickel-Catalyzed N-Arylation of Cyclopropylamine and Related Ammonium Salts with (Hetero)aryl (Pseudo)halides at Room Temperature

안전성 정보

• 픽토그램: GHS08,GHS07,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H302 + H312 + H332,H341,H351,H372,H410
• 예방조치 성명서: P201 - P273 - P280 - P302 + P352 + P312 - P304 + P340 + P312 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Muta. 2 - STOT RE 1 Inhalation
• 표적 기관: Respiratory Tract,Skin
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable