751413
Di(1-adamantyl)-2-dimethylaminophenylphosphine
98%
동의어(들):
2-(Di-1-adamantylphosphino)-N,N-dimethylaniline, 2-(Di-1-adamantylphosphino)dimethylaminobenzene, 2-[Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-N,N-dimethylbenzeneamine, Me-Dalphos
About This Item
추천 제품
![Chloro[di(1-adamantyl)-2-dimethylaminophenylphosphine]gold(I) 97%](/deepweb/assets/sigmaaldrich/product/structures/297/796/103babd8-5537-4e4f-8dd3-c1f5173a0557/640/103babd8-5537-4e4f-8dd3-c1f5173a0557.png)
![(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate](/deepweb/assets/sigmaaldrich/product/structures/216/222/abe04540-8e4f-41fc-bcb8-2e1e0f25c8b9/640/abe04540-8e4f-41fc-bcb8-2e1e0f25c8b9.png)
![5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole 97%](/deepweb/assets/sigmaaldrich/product/structures/334/020/2da77724-fc86-4d88-bc93-0b43ae777daa/640/2da77724-fc86-4d88-bc93-0b43ae777daa.png)
Quality Level
분석
98%
양식
solid
반응 적합성
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
mp
237-242 °C
작용기
phosphine
SMILES string
CN(C)c1ccccc1P([C@@]23C[C@@H]4C[C@@H](C[C@@H](C4)C2)C3)[C@@]56C[C@@H]7C[C@@H](C[C@@H](C7)C5)C6
InChI
1S/C28H40NP/c1-29(2)25-5-3-4-6-26(25)30(27-13-19-7-20(14-27)9-21(8-19)15-27)28-16-22-10-23(17-28)12-24(11-22)18-28/h3-6,19-24H,7-18H2,1-2H3/t19-,20+,21-,22-,23+,24-,27-,28-
InChI key
MILNYLCUWRWYBI-XMCXLQRDSA-N
관련 카테고리
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
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이미 열람한 고객
![5-(Di-tert-butylphosphino)-1′, 3′, 5′-triphenyl-1′H-[1,4′]bipyrazole 97%](/deepweb/assets/sigmaaldrich/product/structures/137/599/8b2f4b58-3384-40aa-9295-0887f7985525/640/8b2f4b58-3384-40aa-9295-0887f7985525.png)
문서
DalPhos is air-stable and contains the bulky di(1-adamantyl)phosphino [P(1-Ad)2] fragment. These ligands are useful in Pd-catalyzed C-N and C-C bond formation. Both Me-DalPhos and Mor-DalPhos allow for Pd-catalyzed ammonia, hydrazine and acetone cross-coupling with good functional group tolerance
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