673013

2-Benzyloxyphenylmagnesium bromide solution

1.0 M in THF

• 실험식(Hill 표기법): C₁₃H₁₁BrMgO
• CAS Number: 328000-16-4
• Molecular Weight: 287.43
• MDL number: MFCD08705262
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24885138
• NACRES: NA.22

속성

• 반응 적합성: reaction type: Grignard Reaction
• 농도: 1.0 M in THF
• density: 1.047 g/mL at 25 °C
• 작용기: phenyl
• SMILES string: Br[Mg]c1ccccc1OCc2ccccc2
• InChI: 1S/C13H11O.BrH.Mg/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13;;/h1-9H,11H2;1H;/q;;+1/p-1
• InChI key: VELKJPFZDYXBDE-UHFFFAOYSA-M

설명

애플리케이션

2-Benzyloxyphenylmagnesium bromide can be used:

• As a substrate in the iron-catalyzed coupling reaction of aryl Grignard reagents with unprotected bromophenols.
• As a substrate in the cross-coupling of Grignard reagents using diaryl titanates and ferric chloride.
• In one of the key synthetic steps for the total synthesis of an antibiotic caboxamycin.

안전성 정보

• 픽토그램: GHS02,GHS08,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H302,H314,H335,H351
• 예방조치 성명서: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 표적 기관: Respiratory system
• 보충제 위험성: EUH014,EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): -4.0 - 5.0 °F - closed cup
• Flash Point (°C): -20 - -15 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter