추천 제품
반응 적합성
reaction type: Grignard Reaction
농도
0.5 M in THF
bp
65 °C (lit.)
density
0.970 g/mL at 25 °C (lit.)
저장 온도
2-8°C
SMILES string
Br[Mg]c1cc2ccccc2c3ccccc13
InChI
1S/C14H9.BrH.Mg/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13;;/h1-9H;1H;/q;;+1/p-1
InChI key
ACMUZKQPXSHTGB-UHFFFAOYSA-M
일반 설명
9-phenanthrylmagnesium bromide is a Grignard reagent. It can be prepared using magnesium turnings and 9-bromophenanthrene under anhydrous condition.
애플리케이션
9-Phenanthrylmagnesium bromide can be used as a reagent to prepare:
- 9-alkyl and 9-arylthiophenanthrenes by reacting with alkyl or aryl thiol compounds.
- (S)-α-methylbenzyl 1-(9-phenanthryl)-2-naphthoate by treating with (S)- α -methylbenzyl methoxy-2-naphthoate.
- 1-(9-Phenanthryl)-1-phenylethanol (carbinol) by reacting with acetophenone. The obtained carbinol undergoes dehydration reaction in the presence of acetic acid and sulfuric acid to afford 1-(9-phenanthryl)-1-phenylethene (PPE).
법적 정보
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
표적 기관
Respiratory system
보충제 위험성
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
The use of the DPE radical polymerization method for the synthesis of chromophore-labelled polymers and block copolymers
European Polymer Journal, 41(6), 1265-1271 (2005)
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