394262

Octadecylmagnesium chloride solution

0.5 M in THF

• 동의어(들): Chlorooctadecylmagnesium, Octadecane, magnesium complex
• Linear Formula: CH₃(CH₂)₁₇MgCl
• CAS Number: 116980-66-6
• Molecular Weight: 313.24
• MDL number: MFCD00012233
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24864583
• NACRES: NA.22

속성

• 반응 적합성: reaction type: Grignard Reaction
• 농도: 0.5 M in THF
• bp: 67 °C
• density: 0.906 g/mL at 25 °C
• SMILES string: CCCCCCCCCCCCCCCCCC[Mg]Cl
• InChI: 1S/C18H37.ClH.Mg/c1-3-5-7-9-11-13-15-17-18-16-14-12-10-8-6-4-2;;/h1,3-18H2,2H3;1H;/q;;+1/p-1
• InChI key: ONJPXWZQVLKGIU-UHFFFAOYSA-M

설명

일반 설명

Octadecylmagnesium chloride is a Grignard reagent commonly used in organic synthesis for various transformations, including nucleophilic addition reactions and carbon-carbon bond formation via palladium-catalyzed alkylation and arylation reactions.

애플리케이션

Octadecylmagnesium chloride can be used for the introduction of octyl substituents on the bipyridine skeletons to prepare functionalized 4,4′-bipyridines, which are used as linkers formation of discrete metal complexes.

안전성 정보

• 픽토그램: GHS02,GHS08,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H302,H314,H335,H351
• 예방조치 성명서: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 표적 기관: Respiratory system
• 보충제 위험성: EUH014,EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 1
• Flash Point (°F): -4.0 °F - closed cup
• Flash Point (°C): -20 °C - closed cup
• 개인 보호 장비: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter