371440
(1-tert-Butylvinyloxy)trimethylsilane
98%
동의어(들):
(2,2-Dimethyl-1-methylenepropoxy)trimethylsilane, 3,3-Dimethyl-2-trimethylsiloxy-1-butene, Pinacolone enol trimethylsilyl ether
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모든 사진(1)
About This Item
Linear Formula:
(CH3)3CC(=CH2)OSi(CH3)3
CAS Number:
Molecular Weight:
172.34
Beilstein:
2204704
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
추천 제품
분석
98%
양식
liquid
refractive index
n20/D 1.409 (lit.)
bp
140-142 °C (lit.)
density
0.798 g/mL at 25 °C (lit.)
SMILES string
CC(C)(C)C(=C)O[Si](C)(C)C
InChI
1S/C9H20OSi/c1-8(9(2,3)4)10-11(5,6)7/h1H2,2-7H3
InChI key
PEHJULPJEVIIFJ-UHFFFAOYSA-N
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일반 설명
(1-tert-Butylvinyloxy)trimethylsilane is a silyl enol. It belongs to organosilicone class of compounds. Enthalpy of vaporization of (1-tert-Butylvinyloxy)trimethylsilane at boiling point has been reported.
애플리케이션
(1-tert-Butylvinyloxy)trimethylsilane ((2,2-Dimethyl-1-methylenepropoxy)trimethylsilane) may be used in the synthesis of cis-3,3-dimethyl-1-(6-phenethyl-3,6-dihydro-2H-pyran-2-yl)butan-2-one.
(1-tert-Butylvinyloxy)trimethylsilane may be used in the preparation of 1-(4-bromophenyl)-4,4-dimethylpentan-3-one.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
75.2 °F - closed cup
Flash Point (°C)
24 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Yaws CL.
Thermophysical Properties of Chemicals and Hydrocarbons, 574-574 (2014)
Salvatore Ferla et al.
Journal of medicinal chemistry, 57(18), 7702-7715 (2014-08-26)
The synthesis of imidazole styrylbenzamide, tert-butyl styrylimidazole, and tert-butyl styrylsulfonate derivatives is described. Evaluation of binding affinity and inhibitory activity against CYP24A1 identified the imidazole styrylbenzamides as potent inhibitors of CYP24A1, having selectivity with respect to CYP27B1 comparable with or
Robert J Hinkle et al.
Tetrahedron, 65(34), 6834-6839 (2010-02-18)
The rapid synthesis of cis-2,6-disubstituted dihydropyrans is achieved in a three-component, one-pot cascade reaction. BiBr(3)-ediated addition of ketene silyl acetals or silyl enol ethers to beta,gamma-unsaturated cis-4-trimethylsilyl-3-butenal provides a Mukaiyama aldol adduct containing a vinylsilane moiety tethered to a silyl
Global Trade Item Number
SKU | GTIN |
---|---|
371440-5G | 4061837678721 |
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