376078

(Isopropenyloxy)trimethylsilane

≥85%

• 동의어(들): 2-(Trimethylsiloxy)propene, Acetone enol trimethylsilyl ether, IPOTMS
• Linear Formula: CH₃C(=CH₂)OSi(CH₃)₃
• CAS Number: 1833-53-0
• Molecular Weight: 130.26
• Beilstein: 1849023
• EC Number: 217-393-1
• MDL number: MFCD00042845
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24863419
• NACRES: NA.22

속성

• 분석: ≥85%
• 형태: liquid
• 불순물: 10-15% hexamethyldisiloxane
• refractive index: n20/D 1.395 (lit.)
• density: 0.78 g/mL at 25 °C (lit.)
• 저장 온도: −20°C
• SMILES string: CC(=C)O[Si](C)(C)C
• InChI: 1S/C6H14OSi/c1-6(2)7-8(3,4)5/h1H2,2-5H3
• InChI key: UAIFZYSPVVBOPN-UHFFFAOYSA-N

설명

일반 설명

(Isopropenyloxy)trimethylsilane is an enol silyl ether. It participates as nucleophile in Lewis acid-promoted C3-nucleophile substitution of tetracyclic bromide. It is reported to participate in the total synthesis of (±)-powelline. It is reported to participate in dityltin bis(triflate) catalyzed Michael addition reaction of enol silyl ethers.

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H315,H319,H335
• 예방조치 성명서: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): 19.4 °F - closed cup
• Flash Point (°C): -7 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter