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Key Documents

추가 자료

333670

Sigma-Aldrich

Tris(trimethylsilyl)phosphine

95%

동의어(들):

(P(TMS)3), Tris(trimethylsilyl)phosphane

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About This Item

Linear Formula:
[(CH3)3Si]3P
CAS Number:
15573-38-3
Molecular Weight:
250.54
MDL number:
MFCD00015487
UNSPSC 코드:
12161700
PubChem Substance ID:
24860167
NACRES:
NA.22

Quality Level

100

분석

95%

형태

liquid

반응 적합성

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

refractive index

n20/D 1.502 (lit.)

bp

243-244 °C (lit.)

density

0.863 g/mL at 25 °C (lit.)

작용기

phosphine

저장 온도

2-8°C

SMILES string

C[Si](C)(C)P([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C9H27PSi3/c1-11(2,3)10(12(4,5)6)13(7,8)9/h1-9H3

InChI key

OUMZKMRZMVDEOF-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

Tris(trimethylsilyl)phosphine (P(TMS)3) can be used as a precursor for the syntheses of:
  • Indium phosphide (InP) and indium gallium phosphide (InGaP) nanocrystals, type III-V semiconductors.
  • Chiral TMS-phospholane which can be further used to synthesize various bisphospholane ligands for asymmetric catalysis.

픽토그램

FlameExclamation mark
GHS02,GHS07

신호어

Danger

유해 및 위험 성명서

H250,H261,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Pyr. Liq. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 2

표적 기관

Respiratory system

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

시험 성적서(COA)

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Sigma-Aldrich

395099

Tris(4-fluorophenyl)phosphine

Zinc phosphide ≥19% active phoshor (P) basis, powder

Sigma-Aldrich

04502

Zinc phosphide

Houman Bahmani Jalali et al.
ACS nano, 12(8), 8104-8114 (2018-07-19)
Light-induced stimulation of neurons via photoactive surfaces offers rich opportunities for the development of therapeutic methods and high-resolution retinal prosthetic devices. Quantum dots serve as an attractive building block for such surfaces, as they can be easily functionalized to match
Microwave-enhanced reaction rates for nanoparticle synthesis.
Gerbec JA, et al.
Journal of the American Chemical Society, 127(45), 15791-15800 (2005)
Synthesis of a new chiral bisphospholane ligand for the Rh (I)-catalyzed enantioselective hydrogenation of isomeric β-acylamido acrylates.
Holz J, et al.
The Journal of Organic Chemistry, 68(5), 1701-1707 (2003)
Formation of high quality InP and InAs nanocrystals in a noncoordinating solvent.
Battaglia D and Peng X
Nano Letters, 2(9), 1027-1030 (2002)
Francesca Pietra et al.
Chemistry of materials : a publication of the American Chemical Society, 29(12), 5192-5199 (2017-07-15)
In this work, we demonstrate that a preferential Ga-for-Zn cation exchange is responsible for the increase in photoluminescence that is observed when gallium oleate is added to InZnP alloy QDs. By exposing InZnP QDs with varying Zn/In ratios to gallium
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