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  • Ga for Zn Cation Exchange Allows for Highly Luminescent and Photostable InZnP-Based Quantum Dots.

Ga for Zn Cation Exchange Allows for Highly Luminescent and Photostable InZnP-Based Quantum Dots.

Chemistry of materials : a publication of the American Chemical Society (2017-07-15)
Francesca Pietra, Nicholas Kirkwood, Luca De Trizio, Anne W Hoekstra, Lennart Kleibergen, Nicolas Renaud, Rolf Koole, Patrick Baesjou, Liberato Manna, Arjan J Houtepen
초록

In this work, we demonstrate that a preferential Ga-for-Zn cation exchange is responsible for the increase in photoluminescence that is observed when gallium oleate is added to InZnP alloy QDs. By exposing InZnP QDs with varying Zn/In ratios to gallium oleate and monitoring their optical properties, composition, and size, we conclude that Ga

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Sigma-Aldrich
1-Octadecene, ≥95.0% (GC)
Sigma-Aldrich
Tris(trimethylsilyl)phosphine, 95%