331023
Nonafluoro-tert-butyl alcohol
99%
동의어(들):
1,1,1,3,3,3-Hexafluoro-2-trifluoromethyl-2-propanol, Perfluoro-tert-butyl alcohol
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모든 사진(1)
About This Item
Linear Formula:
(CF3)3COH
CAS Number:
Molecular Weight:
236.04
Beilstein:
1841640
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.05
추천 제품
vapor pressure
5.19 psi ( 20 °C)
분석
99%
형태
liquid
refractive index
n20/D 1.3 (lit.)
bp
45 °C (lit.)
density
1.693 g/mL at 25 °C (lit.)
작용기
fluoro
SMILES string
OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F
InChI
1S/C4HF9O/c5-2(6,7)1(14,3(8,9)10)4(11,12)13/h14H
InChI key
XZNOAVNRSFURIR-UHFFFAOYSA-N
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일반 설명
Nonafluoro-tert-butyl alcohol is also referred as perfluorotertiarybutanol and ′artificial blood′.
애플리케이션
Nonafluoro-tert-butyl alcohol was employed as a precursor for the preparation of appropriate bis(polyfluoroalkoxymethyl)carbinols and their corresponding mesylates.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
개인 보호 장비
Eyeshields, Faceshields, Gloves
이미 열람한 고객
Huan Meng et al.
Organic letters, 21(13), 5206-5210 (2019-06-30)
A highly efficient method to incorporate the nonafluoro- tert-butoxy group into various arenes is developed. This C-O cross-coupling reaction proceeds smoothly in the absence of transition-metal catalyst with good functional group tolerance and scalability. In comparison with the conventional approach
Greener fluorous chemistry: Convenient preparation of new types of 'CF< sub> 3</sub>-rich'secondary alkyl mesylates and their use for the synthesis of azides, amines, imidazoles and imidazolium salts
Nemes A, et al.
Journal of Fluorine Chemistry, 131(12), 1368-1376 (2010)
Cyclization and rearrangement products from coupling reactions between terminal< i> o</i>-alkynylphenols or< i> o</i>-ethynyl (hydroxymethyl) benzene and 6-halopurines.
Berg TC, et al.
Tetrahedron, 62(25), 6121-6131 (2006)
Maxime Bourguignon et al.
Macromolecular rapid communications, 42(3), e2000482-e2000482 (2020-10-14)
Polyurethane hydrogels are attractive materials finding multiple applications in various sectors of prime importance; however, they are still prepared by the toxic isocyanate chemistry. Herein the facile and direct preparation in water at room temperature of a large palette of
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