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Merck
모든 사진(2)

주요 문서

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276316

Sigma-Aldrich

1-Bromo-3,5-dimethylbenzene

97%

동의어(들):

5-Bromo-m-xylene

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모든 사진(2)

About This Item

Linear Formula:
(CH3)2C6H3Br
CAS Number:
556-96-7
Molecular Weight:
185.06
MDL number:
MFCD00000087
UNSPSC 코드:
12352100
PubChem Substance ID:
24856700
NACRES:
NA.22

분석

97%

양식

liquid

refractive index

n20/D 1.549 (lit.)

bp

202-204 °C (lit.)

density

1.362 g/mL at 25 °C (lit.)

작용기

bromo

SMILES string

Cc1cc(C)cc(Br)c1

InChI

1S/C8H9Br/c1-6-3-7(2)5-8(9)4-6/h3-5H,1-2H3

InChI key

LMFRTSBQRLSJHC-UHFFFAOYSA-N

일반 설명

Palladium catalyzed carbon-oxygen coupling of 1-bromo-3,5-dimethylbenzene and o-cresol to potassium hydroxide to produce o-tolyl-3,5-xylyl ether has been reported.

애플리케이션

1-Bromo-3,5-dimethylbenzene has been used in the synthesis of substituted 2,2′-bis(diphenylphosphanylmethyl)-1,1′-binaphthyl derivatives.

픽토그램

Exclamation mark
GHS07

신호어

Warning

유해 및 위험 성명서

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

188.6 °F - closed cup

Flash Point (°C)

87 °C - closed cup

개인 보호 장비

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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시험 성적서(COA)

Lot/Batch Number
MKCM6046
MKCF7018
MKBW9876V
MKBR6053V
MKBQ9288V

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문서 라이브러리 방문

Highly Selective Catalyst Systems for the Hydroformylation of Internal Olefins to Linear Aldehydes This work was supported by Oxeno Olefinchemie GmbH and the State of Mecklenburg-West Pommerania. Dr. C. Fischer and Mrs. S. Buchholz are thanked for their excellent technical support.
Holger Klein et al.
Angewandte Chemie (International ed. in English), 40(18), 3408-3411 (2001-10-10)
Vittoria M Blasucci et al.
The journal of physical chemistry. A, 114(11), 3932-3938 (2010-03-20)
Tunable solvent systems couple homogeneous catalytic reactions to heterogeneous separations, thereby combining multiple unit operations into a single step and subsequently reducing waste generation and improving process economics. In addition, tunable solvents can require less energy than traditional separations, such
Tapan K Pal et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(52), 19064-19070 (2015-11-21)
By using a bent tetracarboxylic acid ligand that incorporates a pendent-NH2 functional group, a 3D Zn(II)-framework (1) based on Zn2 (CO2)4 secondary building units and Zn12 (CO2)24 supramolecular building blocks has been synthesized. Framework 1 is thermally less stable, which

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