273031

3-Chloroperbenzoic acid

≤77%

• 동의어(들): meta-Chloroperbenzoic acid, 3-Chloroperoxybenzoic acid, MCPBA
• Linear Formula: ClC₆H₄CO₃H
• CAS Number: 937-14-4
• Molecular Weight: 172.57
• Beilstein: 608317
• MDL number: MFCD00002127
• UNSPSC 코드: 12352302
• PubChem Substance ID: 24856527
• NACRES: NA.22

속성

• 분석: ≤77%
• 양식: solid
• 반응 적합성: reagent type: oxidant
• mp: 69-71 °C (lit.)
• 작용기: chloro; hydroperoxide
• 저장 온도: 2-8°C
• SMILES string: OOC(=O)c1cccc(Cl)c1
• InChI: 1S/C7H5ClO3/c8-6-3-1-2-5(4-6)7(9)11-10/h1-4,10H
• InChI key: NHQDETIJWKXCTC-UHFFFAOYSA-N

설명

일반 설명

3-Chloroperbenzoic acid is a strong oxidizing agent mainly used for the epoxidation of alkenes and also in the Baeyer-Villiger oxidation of ketones to esters.

애플리케이션

3-Chloroperbenzoic acid has been used in the oxidation of N-p-tolylsulfinyl-(E)-1-phenylethylideneimine to N-p-tolylsulfonyl (E)-1-phenylethylideneimine using dichloromethane as a solvent. It has also been used in the preparation of mono- and di-epoxy-functionalized poly(3-hydroxybutyrate)-based reactive polymers. MCPBA is also an effective oxidizing agent for conversion of α-amide substituted polyesters to their corresponding polysulfones with tunable thermal properties.

Effective oxidant for epoxidizing di-, tri-, and tetra-substituted olefins.

기타 정보

remainder 3-chlorobenzoic acid and water

안전성 정보

• 픽토그램: GHS02,GHS05,GHS07,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H242,H314,H317,H410
• 예방조치 성명서: P210 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1
• Storage Class Code: 5.2 - Organic peroxides and self-reacting hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges