271411

Allyltributylstannane

97%

• 동의어(들): Allyltri-n-butyltin, Allyltributyltin, Tributyl-2-propenylstannane
• Linear Formula: CH₂=CHCH₂Sn(CH₂CH₂CH₂CH₃)₃
• CAS Number: 24850-33-7
• Molecular Weight: 331.12
• Beilstein: 3588340
• EC Number: 246-494-3
• MDL number: MFCD00010346
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24856436
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 형태: liquid
• refractive index: n20/D 1.486 (lit.)
• bp: 88-92 °C/0.2 mmHg (lit.)
• density: 1.068 g/mL at 25 °C (lit.)
• SMILES string: CCCC[Sn](CCCC)(CCCC)CC=C
• InChI: 1S/3C4H9.C3H5.Sn/c3*1-3-4-2;1-3-2;/h3*1,3-4H2,2H3;3H,1-2H2;
• InChI key: YLGRTLMDMVAFNI-UHFFFAOYSA-N

설명

애플리케이션

Allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595). Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones and allyl acetates.
Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.

안전성 정보

• 픽토그램: GHS06,GHS08,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H301 - H312 - H315 - H319 - H360FD - H372 - H410
• 예방조치 성명서: P202 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1
• Storage Class Code: 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point (°F): 217.4 °F - closed cup
• Flash Point (°C): 103 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter