추천 제품
Quality Level
분석
99%
양식
crystals
반응 적합성
core: ruthenium
reaction type: C-H Activation
reagent type: catalyst
SMILES string
[Ru].[Ru].[Ru].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/12CO.3Ru/c12*1-2;;;
InChI key
NQZFAUXPNWSLBI-UHFFFAOYSA-N
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일반 설명
Atomic number of base material: 44 Ruthenium
애플리케이션
Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates. The phosphine-stabilized carbonyl cluster has been tethered to oxide supports. Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.
Catalyst used in a [3+2+1] carbonylative cycloaddition of silylacteylenes and α,ß-unsaturated ketones providing good yields of α-pyrones.
신호어
Warning
유해 및 위험 성명서
예방조치 성명서
Hazard Classifications
Acute Tox. 4 Inhalation
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
이미 열람한 고객
Journal of the American Chemical Society, 106, 4647-4647 (1984)
Ajeet Singh et al.
Dalton transactions (Cambridge, England : 2003), 47(39), 14033-14040 (2018-09-21)
The synthesis of pyridine alcohol based ruthenium carbonyl clusters Ru3(hep)2(CO)8 (1), Ru3(hpp)2(CO)8 (2), and Ru3(bhmp-H)2(CO)8 (3) {hep-H = 2-(2-hydroxyethyl)pyridine, hpp-H = 2-(3-hydroxypropyl)pyridine and bhmp-H2 = 2,6-bis(hydroxymethyl)pyridine} has been carried out by the reaction of the corresponding pyridine-alcohol ligands with Ru3(CO)12.
Ragaini, F. et al.
Organometallics, 18, 929-929 (1999)
Takahide Fukuyama et al.
Organic letters, 9(4), 587-589 (2007-01-25)
Ruthenium catalyzes a carbonylative [3+2+1] cycloaddition, using silylacetylenes, alpha,beta-unsaturated ketones, and CO as the starting materials, providing the new method for the synthesis of tetrasubstituted alpha-pyrones. In this reaction, the carbonyl group and alpha-carbon of vinyl ketones are incorporated as
J. Chem. Soc., Dalton Trans., 2649-2649 (1988)
문서
High Purity Metalorganic Precursors for CPV Device Fabrication
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