추천 제품
분석
98%
형태
liquid
refractive index
n20/D 1.389 (lit.)
bp
101 °C/74 mmHg (lit.)
mp
18-19 °C (lit.)
density
0.811 g/mL at 25 °C (lit.)
SMILES string
CC(C)(C)OB(OC(C)(C)C)OC(C)(C)C
InChI
1S/C12H27BO3/c1-10(2,3)14-13(15-11(4,5)6)16-12(7,8)9/h1-9H3
InChI key
ZMCWFMOZBTXGKI-UHFFFAOYSA-N
일반 설명
Tri-tert-butyl borate is an organoborate commonly used to prepare other borate esters. It is also used as a substrate in Rh-catalyzed carbonylation reactions.
애플리케이션
Tri-tert-butyl borate can be used as:
- An additive in the synthesis of chiral α-hydroxy esters by reacting dimethylzinc with α-ketoesters using (−)-2-exo-morpholinoisobornane-10-thiol.
- A starting material in the synthesis of boronate of (+)-pinane-2,3-diol.
이미 열람한 고객
Tri?tert ?butylborate
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2012)
Asymmetric addition of dimethylzinc to α-ketoesters catalyzed by (−)-MITH
The Journal of Organic Chemistry, 73(16), 6445-6447 (2008)
Tri?tert ?butylborate
e-EROS Encyclopedia of Reagents for Organic Synthesis (2012)
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