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Merck
모든 사진(2)

주요 문서

227609

Sigma-Aldrich

Decaborane(14)

white

동의어(들):

Boron hydride, Decaborane, Decaboron tetradecahydride, NSC 39828, Tetradecahydrodecaborane, nido-Decaborane(14)

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About This Item

Linear Formula:
B10H14
CAS Number:
Molecular Weight:
122.22
EC Number:
MDL number:
UNSPSC 코드:
12352000

vapor pressure

0.15 mmHg ( 20 °C)

Quality Level

양식

solid

반응 적합성

reagent type: reductant

색상

white

bp

213 °C (lit.)

mp

98-100 °C (lit.)

density

0.94 g/mL at 25 °C (lit.)

SMILES string

[BH]4321[BH]765[BH]984[BH]%11%103[BH]%13%122[BH]%1471[BH]%156([BH]%1695[BH]%118([H]%10)[H]%16)[BH]%14%13([H]%12)[H]%15

InChI

1S/B10H14/c11-5-1-2-3(1,5)7(2,9(3,5,11)13-7)8(2)4(1,2)6(1,5)10(4,8,12-6)14-8/h1-10H

InChI key

XAMMYYSPUSIWAS-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

Boron source for ion-implantation processes.
Reactant for:
  • Chemical vapor deposition of boron nitride nanosheets on Ni or Cu foils in the presence of ammonia
  • Stereoselective catalytic hydrogenation reactions
  • Chemical hydrogen storage
  • Preparation of carborane-conjugated quinoline carboxamide ligands of translocator protein for boron neutron capture therapy (BNCT)
  • Synthesis of hydrogenated boron clusters B12Hn with controlled hydrogen content
  • Preparation of alkenyldecaboranes by regioselective transition-metal-catalyzed decaborane-alkyne hydroboration reactions

픽토그램

FlameSkull and crossbones

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges


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문서 라이브러리 방문

Kiminori Ohta et al.
Bioorganic & medicinal chemistry letters, 14(23), 5913-5918 (2004-10-27)
We designed and synthesized novel retinoid X receptor (RXR)-selective antagonists bearing a carborane moiety. Compounds 8a-d or 9a-d themselves have no differentiation-inducing activity toward HL-60 cells and no inhibitory activity towards a retinoic acid receptor (RAR) agonist. However, they inhibit
Zhu Yinghuai et al.
Journal of the American Chemical Society, 129(20), 6507-6512 (2007-05-03)
Well dispersed ruthenium(0) nanoparticles, stabilized in the ionic liquid agent, trihexyltetradecylphosphonium dodecylbenzenesulfonate, have been successfully prepared via a reduction reaction of the precursor [CpRuCp*RuCp*]PF6 (Cp* = C5Me5). The ruthenium(0) nanoparticles were shown to catalyze the isotope exchange reaction between 10B
Ilias Sioutis et al.
The journal of physical chemistry. A, 110(45), 12528-12534 (2006-11-10)
The interaction of decaborane (B(10)H(14)) with the I(-) ion and the (isoelectronic) Xe atom is investigated using a number of theoretical methods: MP2, CCSD(T), CCSD, spin-orbit CISD, and DFT using the B3LYP, B3PW91, PW91PW91, and PBE0 methods. All non-DFT and
Yuqi Li et al.
Inorganic chemistry, 47(20), 9193-9202 (2008-09-20)
Unlike in conventional organic solvents, where Lewis base catalysts are required, decaborane dehydrogenative alkyne-insertion reactions proceed rapidly in biphasic ionic-liquid/toluene mixtures with a wide variety of terminal and internal alkynes, thus providing efficient, one-step routes to functional o-carborane 1-R-1,2-C2B10H11 and

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