추천 제품
Quality Level
분석
99%
양식
powder
반응 적합성
core: aluminum
reagent type: catalyst
mp
200-251 °C (dec.)
SMILES string
CC(=O)\C=C(\C)O[Pd]O\C(C)=C/C(C)=O
InChI
1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
InChI key
JKDRQYIYVJVOPF-FDGPNNRMSA-L
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일반 설명
Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.
애플리케이션
Palladium(II) acetylacetonate (Pd(acac)2) was used in the following studies:
- Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).
- Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.
- As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
이미 열람한 고객
Lukas J Goossen et al.
Journal of the American Chemical Society, 129(15), 4824-4833 (2007-03-23)
A new strategy for the regiospecific construction of unsymmetrical biaryls is presented, in which easily available salts of carboxylic acids are decarboxylated in situ to give arylmetal species that serve as the nucleophilic component in a catalytic cross-coupling reaction with
Sublimation and deposition behaviour of palladium (II) acetylacetonate.
Cominos V and Gavriilidis A.
The European Physical Journal - Applied Physics, 15(01), 23-33 (2001)
Nicolas Marion et al.
Accounts of chemical research, 41(11), 1440-1449 (2008-09-09)
Metal-catalyzed cross-coupling reactions, notably those permitting C-C bond formation, have witnessed a meteoritic development and are now routinely employed as a powerful synthetic tool both in academia and in industry. In this context, palladium is arguably the most studied transition
Sümeyra Diyarbakir et al.
ACS applied materials & interfaces, 7(5), 3199-3206 (2015-01-17)
Monodisperse CuPd alloy nanoparticles (NPs) were prepared by using a typical high-temperature organic solution phase protocol comprising the coreduction of copper(II) acetylacetonate and palladium(II) acetylacetonate by morpholine-borane complex in oleylamine and 1-octadecene solution at 80 °C. The presented synthesis protocol
문서
The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.
High Purity Metalorganic Precursors for CPV Device Fabrication
The properties of many devices are limited by the intrinsic properties of the materials that compose them.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 209015-5G | 4061835511884 |
| 209015-1G | 4061838770455 |
| 209015-250MG |
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