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Merck
모든 사진(2)

주요 문서

142514

Sigma-Aldrich

3-Bromopropionyl chloride

technical grade

동의어(들):

β-Bromopropanoyl chloride, β-Bromopropionyl chloride, ψ-Bromopropanoyl chloride, 3-Bromopropanoic acid chloride, 3-Bromopropanoyl chloride

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About This Item

Linear Formula:
BrCH2CH2COCl
CAS Number:
Molecular Weight:
171.42
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

Grade

technical grade

Quality Level

양식

liquid

refractive index

n20/D 1.49 (lit.)

bp

55-57 °C/17 mmHg (lit.)

density

1.701 g/mL at 25 °C (lit.)

작용기

acyl chloride
bromo

저장 온도

2-8°C

SMILES string

ClC(=O)CCBr

InChI

1S/C3H4BrClO/c4-2-1-3(5)6/h1-2H2

InChI key

IHBVNSPHKMCPST-UHFFFAOYSA-N

일반 설명

3-Bromopropionyl chloride reacts with poly(ethylene glycol) methacrylate to yield brominated poly(ethylene glycol) methacrylate. It causes the acylation of 4-aryl-substituted 3,4-di-hydropyrimidine(1H)-2-thiones to give bicyclic pyrimido[2,1-b][1,3]thiazines.

애플리케이션

3-Bromopropionyl chloride was used in the preparation of 1-chloro-4-bromo-2-butanone.

픽토그램

CorrosionExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Skin Corr. 1B - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point (°F)

174.2 °F - closed cup

Flash Point (°C)

79 °C - closed cup

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Synthesis of bicyclic pyrimido [2, 1-b][1, 3] thiazines based on 3, 4-dihydropyrimidine-(1H)-2-thiones.
Kulakov IV and Turdybekov DM.
Chemistry of Heterocyclic Compounds, 46(3), 342-346 (2010)
Synthesis and Characterization of a Novel Macromonomer Initiator for Reversible Addition Fragmentation Chain Transfer (RAFT). Evaluation of the Polymerization Kinetics and Gelation Behaviors.
Ozturk T and Hazer B.
Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 47(3), 265-272 (2010)
A Nagy et al.
Proceedings of the National Academy of Sciences of the United States of America, 93(6), 2464-2469 (1996-03-19)
A convenient, high yield conversion of doxorubicin to 3'-deamino-3'-(2''-pyrroline-1''-yl)doxorubicin is described. This daunosamine-modified analog of doxorubicin is 500-1000 times more active in vitro than doxorubicin. The conversion is effected by using a 30-fold excess of 4-iodobutyraldehyde in anhydrous dimethylformamide. The
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Polystyrene-based polymers with variable molecular weights are prepared by radical polymerization of styrene. Polystyrene is grafted with bromo-alkyl chains of different lengths through Friedel-Crafts acylation and quaternized to afford a series of hydroxide-ion-conducting ionomers for the catalyst binder for the

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