추천 제품
Grade
technical grade
Quality Level
분석
94%
형태
liquid
반응 적합성
reaction type: C-C Bond Formation
refractive index
n20/D 1.396 (lit.)
bp
102-103 °C/720 mmHg (lit.)
density
0.897 g/mL at 25 °C (lit.)
SMILES string
COC(OC)N(C)C
InChI
1S/C5H13NO2/c1-6(2)5(7-3)8-4/h5H,1-4H3
InChI key
ZSXGLVDWWRXATF-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
애플리케이션
N,N-Dimethylformamide dimethyl acetal (DMF-DMA) can be used as:
- An organocatalyst for the synthesis of 1,2-disubstituted-3,4-dihydronaphthalenes by the reaction of vinylarenes and electron-deficient alkynes.
- A building block for the preparation of heterocyclic compounds such as enamines and amidines via formylation of methylene and amino groups.
- A reagent in the synthesis of 1,4-diaryl-piperazine-2,5-diones by reacting with chloroacetamides.
- A reagent along with enamine and alkyne for the preparation of 2,3,4,5-tetrasubstituted pyridine derivatives by three-component coupling reaction in the presence of Me3SiCl.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Sens. 1
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point (°F)
42.8 °F
Flash Point (°C)
6 °C
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
이미 열람한 고객
Synthesis of 1, 4-Diaryl-piperazine-2, 5-diones: New Behavior of N, N-Dimethylformamide Dimethyl Acetal (DMFDMA)
Synthetic Communications, 38(3), 376-382 (2008)
Organic letters, 8(19), 4247-4250 (2006-09-08)
A novel series of analogues of calcitriol (1) is developed featuring a spirocyclic central core resulting from C18/C21-connection and C15/C16-deletion (2a, 2b). The synthesis of the key intermediate involves an Eschenmoser rearrangement of an enantiomerically pure bromo-substituted cyclohexenol.
A highly efficient cycloaddition of vinylarenes with electron-deficient alkynes affording 1, 2-disubstituted-3, 4-dihydronaphthalenes catalysed by N, N-dimethylformamide dimethyl acetal
Organic & Biomolecular Chemistry, 5(12), 1854-1857 (2007)
Journal of the American Society for Mass Spectrometry, 16(7), 1192-1203 (2005-06-01)
A fragmentation mechanism for the neutral loss of 73 Da from dimethylformamidine glutamine isobutyl ester is investigated. Understanding this mechanism will allow to improve the identification and quantification of 15N-labeled and unlabeled glutamine and the distinguishing of glutamine and glutamic
Organic & biomolecular chemistry, 10(2), 281-286 (2011-11-08)
1-Methylimidazole exhibits an unusually high efficiency in promoting the reaction of aryl methyl ketones with DMF-DMA to form (2E)-1-aryl-3-dimethylamino-2-propenones which lacks correlation between the catalytic efficiency and the basicity of 1-methylimidazole in comparison to other amines. An unprecedented supramolecular domino
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