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Merck
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주요 문서

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113379

Sigma-Aldrich

Chloro(dimethyl)phenylsilane

98%

동의어(들):

DMPSCl, Dimethylphenylchlorosilane, Dimethylphenylsilylchloride, Phenyldimethylchlorosilane

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모든 사진(1)

About This Item

Linear Formula:
C6H5Si(CH3)2Cl
CAS Number:
768-33-2
Molecular Weight:
170.71
Beilstein:
606292
EC Number:
212-193-0
MDL number:
MFCD00000499
UNSPSC 코드:
12352002
PubChem Substance ID:
24846878
NACRES:
NA.22

분석

98%

refractive index

n20/D 1.509 (lit.)

density

1.017 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(Cl)c1ccccc1

InChI

1S/C8H11ClSi/c1-10(2,9)8-6-4-3-5-7-8/h3-7H,1-2H3

InChI key

KWYZNESIGBQHJK-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

Used in a synthesis of enantioenriched allenylsilanes via an ortho-ester Claisen rearrangement of chiral, silylpropargylic alcohols.

픽토그램

Corrosion
GHS05

신호어

Danger

유해 및 위험 성명서

H314

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point (°F)

143.6 °F - closed cup

Flash Point (°C)

62 °C - closed cup

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number
MKCP6165
SHBJ9323
SHBJ6059
SHBF9670V
SHBC5610V

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문서 라이브러리 방문

Carlton P Folster et al.
Dalton transactions (Cambridge, England : 2003), 49(45), 16125-16132 (2020-01-30)
The synthesis of a chloro-functionalized six-membered cyclosilazane (Si5N) is reported. Subsequent reductive polymerizations yielded low molecular weight polysilazanes. 1H and 29Si NMR characterization suggest the identity of the reducing metal influences the polysilazane structure. Optical characterization is consistent with extended
Ryan A Brawn et al.
Organic letters, 9(14), 2689-2692 (2007-06-15)
A convenient procedure for the synthesis of highly enantioenriched allenylsilanes by Johnson orthoester Claisen rearrangement of 1-silyl propargylic alcohols is described. Allenylsilanes are then used as carbon nucleophiles in three-component, Lewis acid mediated additions to in situ generated oxonium ions
M Okamoto
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 112(6), 409-413 (1992-06-01)
The retention behavior and selectivity of 30 kinds of phenyl-modified porous glasses and silicas, prepared from solutions of phenyldimethylchlorosilane, diphenylmethylchlorosilane or triphenylchlorosilane in xylene, were studied by high-performance liquid chromatography using carbamazepine and diphenylhydantoin as model compounds. From the elemental

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