추천 제품
Grade
for GC derivatization
Quality Level
분석
≥97.0% (GC)
형태
liquid
품질
LiChropur™
반응 적합성
reagent type: derivatization reagent
reaction type: Silylations
기술
gas chromatography (GC): suitable
refractive index
n20/D 1.43 (lit.)
bp
142-144 °C (lit.)
density
0.898 g/mL at 25 °C (lit.)
SMILES string
CC[Si](Cl)(CC)CC
InChI
1S/C6H15ClSi/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3
InChI key
DCFKHNIGBAHNSS-UHFFFAOYSA-N
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일반 설명
Chlorotriethylsilane may be used as a silylating reagent for the preparation of trisilyl ethers from alcohols in the presence of a base such as imidazole, pyridine or 4-(dimethylamino)pyridine. It is found to be more reactive when used with pyridine as a solvent.
애플리케이션
Chlorotriethylsilane may be used as a derivatizing reagent for the determination of fluoride, in toothpaste samples using headspace solid-phase microextraction and gas chromatography–flame ionization detection.
기타 정보
Silylating agent with some advantage over the trimethylsilylating agents for synthetic and analytical applications
법적 정보
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A
보충제 위험성
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point (°F)
86.0 °F
Flash Point (°C)
30 °C
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Silylating Agents, 2nd ed. (1995)
Journal of the American Chemical Society, 99, 948-948 (1977)
Determination of fluoride in toothpaste using headspace solid-phase microextraction and gas chromatography?flame ionization detection
Journal of Chromatography A, 1150(1-2), 173-177 (2007)
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 4 (2014)
Journal of Chromatographic Science, 17, 115-115 (1979)
문서
Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs
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