936715

Grubbs Catalyst^® M300 ChemBeads

• 別名: Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)bis(3-bromopyridine)ruthenium(II) ChemBeads, Grubbs Catalyst^® 3rd Generation ChemBeads, Grubbs Catalyst^® C884 ChemBeads, Grubbs Catalyst^® M37a (C884) ChemBeads, [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)bis(3-bromopyridine)ruthenium(II) ChemBeads, [1,3-Dimesityl-2-imidazolidinylidene]dichloro(phenylmethylene)bis(3-bromopyridine)ruthenium(II) ChemBeads
• 実験式（ヒル表記法）: C₃₈H₄₀Br₂Cl₂N₄Ru
• CAS番号: 900169-53-1
• 分子量: 884.54
• UNSPSCコード: 12352300

特性

• 形状: solid
• 品質水準: 100
• 組成: loading of catalyst, 4-6 wt. %
• 反応適合性: reagent type: catalyst; core: ruthenium; reaction type: Ring-Opening Polymerization
• 保管温度: 2-8°C
• SMILES記法: Brc1cccnc1.Brc2cccnc2.Cc3cc(C)c(N4CCN(C4=[Ru](Cl)(Cl)=Cc5ccccc5)c6c(C)cc(C)cc6C)c(C)c3
• InChI: 1S/C21H26N2.C7H6.2C5H4BrN.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-7-5-3-2-4-6-7;2*6-5-2-1-3-7-4-5;;;/h9-12H,7-8H2,1-6H3;1-6H;2*1-4H;2*1H;/q;;;;;;+2/p-2
• InChI Key: YDOACSUCKSODBO-UHFFFAOYSA-L

詳細

詳細

ChemBeads glass beads coated with Grubbs Catalyst^® M300.

アプリケーション

Metathesis: Ruthenium-Based Metathesis Catalysts Labile pyridine ligands result in a very fast initiator (even at 0 °C). Effective in cross metathesis of acrylonitrile. Also effective in RCM and the ROMP production of block copolymers and polymers with narrow PDIs

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

For larger scale uses, product also available in powdered form (682330)

その他情報

Grubbs Catalyst^® Technology for Olefin Metathesis by Aldrich



High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

法的情報

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

安全性情報

• 保管分類コード: 13 - Non Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable