44920

鉄(III)アセチルアセトナート

purum, ≥97.0% (RT)

• 別名: 2,4-ペンタンジオン 鉄(III)誘導体, Fe(acac)₃, 第二鉄アセチルアセトナート, 鉄(III)2,4-ペンタンジオナート
• 化学式: Fe(C₅H₇O₂)₃
• CAS番号: 14024-18-1
• 分子量: 353.17
• Beilstein: 4157960
• EC Number: 237-853-5
• MDL番号: MFCD00000020
• UNSPSCコード: 12352103
• PubChem Substance ID: 329756564
• NACRES: NA.23

特性

• グレード: purum
• 品質水準: 200
• アッセイ: ≥97.0% (RT)
• フォーム: powder
• 反応適合性: core: iron; reagent type: catalyst
• mp: 180-182 °C (dec.) (lit.); 180-190 °C (dec.)
• 密度: 5.24 g/mL at 25 °C (lit.)
• SMILES記法: CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O
• InChI: 1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
• InChI Key: AQBLLJNPHDIAPN-LNTINUHCSA-K

詳細

詳細

Iron(III) acetylacetonate, also known as tris(acetylacetonato)iron(III) or Fe(acac)₃, is a coordination compound that is highly soluble in organic solvents. It is used as a precursor in the preparation of iron-containing materials and thin films, which are important in electronics and coatings. Additionally, it is also as a catalyst in organic reactions, particularly in the synthesis of organic compounds and polymerization processes.

アプリケーション

高結晶性(Zn,Fe)Fe₂O₄膜のMOCVD前駆体と、その膜の磁気的特性の測定用です。

Iron(III) acetylacetonate can be used as:     

• A precursor in the synthesis of Fe₃O₄/carbon composite fibers via forcespinning. This fiber material is suitable for use as anode materials in lithium-ion batteries.     
• A precursor in the synthesis of iron-based metal-organic frameworks (MOFs) for the applications in rechargeable alkali-ion batteries.
• A catalyst in the controlled living radical polymerization of vinyl acetate to synthesis of polymers with controlled molecular weights.   
• A precursor to synthesize iron-doped titania (Fe-TiO₂) photocatalysts for the potential applications in photocatalytic reactions.     
• A MOCVD precursor for highly crystalline (Zn,Fe)Fe₂O₄ films and magnetic property measurements of these films.

その他情報

Catalyst used in Grignard reactions with acid chlorides to give ketones

安全性情報

• ピクトグラム: GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H302 + H312 + H332,H318
• 注意書き: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): dust mask type N95 (US), Eyeshields, Gloves