MX1123

1-Methylimidazole

• 別名: 1-Methylimidazole, N-Methylimidazole, dna
• 化学式: CH₃-NCH=NCH=CH-
• CAS番号: 616-47-7
• MDL番号: MFCD00005292
• UNSPSCコード: 12352100
• EC Index Number: 210-484-7

特性

• 蒸気圧: 0.4 hPa ( 20 °C)
• 品質水準: 200
• 形状: liquid
• pH: 9.5-10.5 (20 °C, 50 g/L in H₂O)
• bp: 198 °C/1013 hPa
• mp: -2 °C
• 転移温度: flash point 92 °C
• 輸送温度: ambient
• 保管温度: room temp
• InChI: 1S/C4H6N2/c1-6-3-2-5-4-6/h2-4H,1H3
• InChI Key: MCTWTZJPVLRJOU-UHFFFAOYSA-N

詳細

アプリケーション

1-Methylimidazole can be used as an organocatalyst to synthesize:

• 4-amino-3,5-dicyano-6-arylphthalates via one-pot, a three-component reaction between arylidenemalononitriles, dialkyl ­acetylenedicarboxylates, and malononitrile.
• Aromatic and aliphatic carbamates from hydroxamic acids via the Lossen rearrangement.
• Tetrahydrobenzo[b]pyrans via three-component cyclocondensation reaction between aromatic aldehydes, malononitrile, and dimedone.

It can also be used as:

• A co-catalyst in copper-catalyzed, greener oxidation of alcohols to carbonyl compounds under aerobic conditions.
• A solvent/complexing agent in the preparation of CuInS₂ n-type semiconductive particles.
• A co-additive in the synthesis of acid-sensitive epoxides by methyltrioxorhenium-catalyzed epoxidation of alkenes with H₂O₂.

アナリシスノート

Assay (GC)99.0% minDensity at 20°C1.03-1.04g/mLFormClear, liquidWater (H2O)150ppm max

安全性情報

• ピクトグラム: GHS06,GHS08,GHS05
• シグナルワード: Danger
• 危険有害性情報: H302,H311,H314,H361d
• 注意書き: P202 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B
• 保管分類コード: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 2
• 引火点(°F): 197.6 °F - closed cup
• 引火点(℃): 92 °C - closed cup