538507

2-アミノ-6-ブロモベンゾチアゾール

97%

• 実験式（ヒル表記法）: C₇H₅BrN₂S
• CAS番号: 15864-32-1
• 分子量: 229.10
• MDL番号: MFCD00152229
• UNSPSCコード: 12352100
• PubChem Substance ID: 24878338
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 97%
• フォーム: solid
• mp: 213-217 °C (lit.)
• 官能基: bromo
• SMILES記法: Nc1nc2ccc(Br)cc2s1
• InChI: 1S/C7H5BrN2S/c8-4-1-2-5-6(3-4)11-7(9)10-5/h1-3H,(H2,9,10)
• InChI Key: VZEBSJIOUMDNLY-UHFFFAOYSA-N

詳細

詳細

Reaction of 4-bromoaniline with acetic acid and potassium thiocynate in solution of bromine in acetic acid yields 2-amino-6-bromobenzothiazole. 2-Amino-6-bromobenzothiazole can also be synthesized from 2-aminobenzothiazole via monobromination with silica-supported quinolinium tribromide.

アプリケーション

2-Amino-6-bromobenzothiazole may be used in the synthesis of the following

• 2-amino-6-arylbenzothiazole compounds:
• 6-p-tolylbenzo[d]thiazole-2-amine
• 6-(4chlorophenyl)benzo[d]thiazole-2-amine
• 6-(4-methoxyphenyl)benzo[d]thiazole-2-amine
• 6-(3,5-bis(triflouromethyl)phenyl)benzo[d]thiazole-2-amine
• 6-phenylbenzo[d]thiazole-2-amine

It may be employed as a ligand (L) in the synthesis of organometallic derivatives of Rh(I) [Rh(CO)₂(L)(Cl)].

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H302,H317,H319
• 注意書き: P261 - P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Sens. 1
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): dust mask type N95 (US), Eyeshields, Faceshields, Gloves