49661

Methyl 4-pentenoate

≥95.0% (GC)

• 別名: アリル酢酸メチル, アリル酢酸メチルエステル
• 実験式（ヒル表記法）: C₆H₁₀O₂
• CAS番号: 818-57-5
• 分子量: 114.14
• MDL番号: MFCD03990590
• UNSPSCコード: 12352100
• PubChem Substance ID: 57651216
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: ≥95.0% (GC)
• 屈折率: n20/D 1.415; n20/D 1.415
• 官能基: allyl; ester
• SMILES記法: COC(=O)CCC=C
• InChI: 1S/C6H10O2/c1-3-4-5-6(7)8-2/h3H,1,4-5H2,2H3
• InChI Key: SHCSFZHSNSGTOP-UHFFFAOYSA-N

詳細

詳細

Methyl 4-pentenoate is an unsaturated methyl ester that is prepared by the esterification of 1-pentenoic acid with methanol. It undergoes amidation with formamide via acetone-initiated photochemical reaction to form a 1:1 adduct. The metathesis of methyl 4-pentenoate with different Mo(VI)alkylidene complexes have been reported. It acts as a chain transfer agent during the polymerization of exo,exo-5,6-bis(methoxymethyl)-7-oxabicyclo[2.2.1]hept-2-ene using Ru^II(H₂0)₆(tos)₂ (tos =p-toluenesulfonate) as a catalyst.

安全性情報

• ピクトグラム: GHS02,GHS07
• シグナルワード: Warning
• 危険有害性情報: H226,H319
• 注意書き: P210 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Flam. Liq. 3
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 84.2 °F - closed cup
• 引火点(℃): 29 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter